具有多个相同螯合单元的大环配体选择性合成异四核配合物

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-03-27 DOI:10.1039/D5DT00623F

Kota Seki and Takashi Nakamura

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引用次数: 0

摘要

选择性络合特定单位在同聚物通常是具有挑战性的，因为他们的相似的反应性。我们现在报道了一种杂核配合物，该配合物使用具有四个相同的ONO螯合单元的大环配体，通过选择性配位在两个对角单元上与钼配合，然后在其余单元上与钯配合合成。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Selective synthesis of a heterotetranuclear complex from a macrocyclic ligand with multiple identical chelating units†

查看原文本刊更多论文

Selective synthesis of a heterotetranuclear complex from a macrocyclic ligand with multiple identical chelating units†

Selective complexation of specific units in homooligomers is usually challenging due to their similar reactivity. We now report a heteronuclear complex using a macrocyclic ligand with four identical ONO chelating units, which was synthesized by selective coordination to molybdenum at two diagonal units, followed by palladium at the remaining units.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.