[BMIM(SO2Cl)][OTs]离子液体中微波辅助快速合成1,2-苯并异恶唑、异恶唑喹啉和异噻唑喹啉

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-03-26 DOI:10.1134/S1070363224611943

I. Jamadar, R. B. Manami, S. Kurahatti, A. Anchi, V. Jadhav, R. G. Kalkhambkar, M. Kurkuri, M. S. Refat, A. M. Alsuhaibani

{"title":"[BMIM(SO2Cl)][OTs]离子液体中微波辅助快速合成1,2-苯并异恶唑、异恶唑喹啉和异噻唑喹啉","authors":"I. Jamadar, R. B. Manami, S. Kurahatti, A. Anchi, V. Jadhav, R. G. Kalkhambkar, M. Kurkuri, M. S. Refat, A. M. Alsuhaibani","doi":"10.1134/S1070363224611943","DOIUrl":null,"url":null,"abstract":"A green method of the synthesis of 1,2-benzisoxazole, isoxazolo- and isothiazolo-quinoline from 2-hydroxyaryl ketoximes in the presence of [BMIM(SO2Cl)][OTs] ionic liquid has been demonstrated under microwave irradiation. The noticeable advantages of this method over other reported methods are less reaction time, simple work-up procedure and excellent yields (85–96%). The method also highlights the reuse and recycle of ionic liquid employed (up to four cycles) with negligible loss of yield.","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 2","pages":"393 - 404"},"PeriodicalIF":0.9000,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microwave-Assisted Facile Synthesis of 1,2-Benzisoxazoles, Isoxazoloquinolines, and Isothiazoloquinolines in [BMIM(SO2Cl)][OTs] Ionic Liquid as a Recyclable System\",\"authors\":\"I. Jamadar, R. B. Manami, S. Kurahatti, A. Anchi, V. Jadhav, R. G. Kalkhambkar, M. Kurkuri, M. S. Refat, A. M. Alsuhaibani\",\"doi\":\"10.1134/S1070363224611943\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A green method of the synthesis of 1,2-benzisoxazole, isoxazolo- and isothiazolo-quinoline from 2-hydroxyaryl ketoximes in the presence of [BMIM(SO2Cl)][OTs] ionic liquid has been demonstrated under microwave irradiation. The noticeable advantages of this method over other reported methods are less reaction time, simple work-up procedure and excellent yields (85–96%). The method also highlights the reuse and recycle of ionic liquid employed (up to four cycles) with negligible loss of yield.\",\"PeriodicalId\":761,\"journal\":{\"name\":\"Russian Journal of General Chemistry\",\"volume\":\"95 2\",\"pages\":\"393 - 404\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2025-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of General Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070363224611943\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of General Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070363224611943","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

研究了在[BMIM(SO2Cl)][OTs]离子液体存在下，微波辐射下由2-羟基酮肟合成1,2-苯并异恶唑、异恶唑和异噻唑喹啉的绿色方法。与其他已报道的方法相比，该方法的显著优点是反应时间短，工序简单，收率高（85-96%）。该方法还强调了离子液体的再利用和再循环（多达四个循环），而产量的损失可以忽略不计。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Microwave-Assisted Facile Synthesis of 1,2-Benzisoxazoles, Isoxazoloquinolines, and Isothiazoloquinolines in [BMIM(SO2Cl)][OTs] Ionic Liquid as a Recyclable System

查看原文本刊更多论文

Microwave-Assisted Facile Synthesis of 1,2-Benzisoxazoles, Isoxazoloquinolines, and Isothiazoloquinolines in [BMIM(SO2Cl)][OTs] Ionic Liquid as a Recyclable System

A green method of the synthesis of 1,2-benzisoxazole, isoxazolo- and isothiazolo-quinoline from 2-hydroxyaryl ketoximes in the presence of [BMIM(SO₂Cl)][OTs] ionic liquid has been demonstrated under microwave irradiation. The noticeable advantages of this method over other reported methods are less reaction time, simple work-up procedure and excellent yields (85–96%). The method also highlights the reuse and recycle of ionic liquid employed (up to four cycles) with negligible loss of yield.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.