三氯化铈的制备及电弧熔化分解

IF 1.5 3区 化学 Q3 CHEMISTRY, ANALYTICAL
Jason Victor, Harry Jang, Andrew Hunter, Paula Ramirez, Daniel Koury, Frederic Poineau, Kenneth Czerwinski
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引用次数: 0

摘要

用CeO2与AlCl3在密封的石英安瓿中反应或用CeO2与CCl4在压力容器中反应制备了三氯化铈。用AlCl3合成的方法可以制备数百毫克量的材料,而无需使用溶剂或流动气体反应。采用粉末x射线衍射(PXRD)、热重分析/差示扫描量热分析(TGA-DSC)和扫描电镜/能量色散x射线能谱(SEM-EDS)对AlCl3制备的CeCl3样品进行了表征。通过弧熔法制备CeCl3,对CeCl3进行热分解,形成CeCl3/CeOCl混合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and arc melting decomposition of cerium trichloride

Cerium trichloride was prepared from the reaction of CeO2 with AlCl3 in a sealed quartz ampoule or from the reaction of CeO2 with CCl4 in a pressure vessel. The synthetic approach with AlCl3 allowed for the preparation of hundreds of milligram quantities of material and bypassed the use of solvents or flowing gas reactions. The CeCl3 sample prepared from AlCl3 was characterized by powder x-ray diffraction (PXRD), thermogravimetric analysis/ differential scanning calorimetry (TGA–DSC) and scanning electron microscopy/energy-dispersive x-ray spectroscopy (SEM–EDS). Thermal decomposition of CeCl3 prepared from CCl4 via arc-melting led to the formation of a CeCl3/CeOCl mixture.

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来源期刊
CiteScore
2.80
自引率
18.80%
发文量
504
审稿时长
2.2 months
期刊介绍: An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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