Selvamani Arumugam*, Nagabhatla Viswanadham*, Anjan Ray, Anup Prakash Tathod, Arumugam Sivasamy, Kalarical Janardhanan Sreeram and Kamal Singh Koranga,
{"title":"通过可持续的碳氢化合物燃料生产动物废物衍生原料的价值","authors":"Selvamani Arumugam*, Nagabhatla Viswanadham*, Anjan Ray, Anup Prakash Tathod, Arumugam Sivasamy, Kalarical Janardhanan Sreeram and Kamal Singh Koranga, ","doi":"10.1021/acssusresmgt.4c0045010.1021/acssusresmgt.4c00450","DOIUrl":null,"url":null,"abstract":"<p >The present study reports the first-of-its-kind process for producing sustainable hydrocarbon fuels from novel bio-feedstocks SBB (slaughterhouse-waste biodiesel byproduct) and PBB (poultry-waste biodiesel byproduct) obtained from animal waste oil-based biodiesel. The process demonstrated that the conversion of those feedstocks and hydrocarbon product selectivity varied according to the catalyst and feedstock properties. The Zn/SBZ catalyst possessing the ideal combination of micro-mesopores and acid sites exhibited 100% conversion for those feedstocks to produce liquid products composed of mainly 72-75% aromatics and 25-28% larger non-aromatics (C<sub>8</sub>–C<sub>15</sub> naphthenes and C<sub>7</sub>–C<sub>12</sub> iso-paraffins) with the research octane number (RON) of 100 suitable for sustainable aviation fuel applications. The Zn/Z catalyst only with micropores and predominant acid sites appears to be a suitable catalyst for gasoline production due to its high aromatic selectivity (83-85%) and favorable RON (105), although it showed relatively low conversion (∼80%). It was also discovered that the SBB’s high hydrocarbon constituents made it a better feedstock for the production of hydrocarbon fuel than the PBB. Overall, the conversion of animal waste into fuel-range hydrocarbons not only provides an eco-friendly solution for waste management but also holds the potential to enhance energy security by reducing the need for fossil fuels, thereby supporting a more sustainable future.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 3","pages":"455–462 455–462"},"PeriodicalIF":0.0000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Valorization of Animal-Waste-Derived Feedstocks through Sustainable Hydrocarbon Fuel Production\",\"authors\":\"Selvamani Arumugam*, Nagabhatla Viswanadham*, Anjan Ray, Anup Prakash Tathod, Arumugam Sivasamy, Kalarical Janardhanan Sreeram and Kamal Singh Koranga, \",\"doi\":\"10.1021/acssusresmgt.4c0045010.1021/acssusresmgt.4c00450\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The present study reports the first-of-its-kind process for producing sustainable hydrocarbon fuels from novel bio-feedstocks SBB (slaughterhouse-waste biodiesel byproduct) and PBB (poultry-waste biodiesel byproduct) obtained from animal waste oil-based biodiesel. The process demonstrated that the conversion of those feedstocks and hydrocarbon product selectivity varied according to the catalyst and feedstock properties. The Zn/SBZ catalyst possessing the ideal combination of micro-mesopores and acid sites exhibited 100% conversion for those feedstocks to produce liquid products composed of mainly 72-75% aromatics and 25-28% larger non-aromatics (C<sub>8</sub>–C<sub>15</sub> naphthenes and C<sub>7</sub>–C<sub>12</sub> iso-paraffins) with the research octane number (RON) of 100 suitable for sustainable aviation fuel applications. The Zn/Z catalyst only with micropores and predominant acid sites appears to be a suitable catalyst for gasoline production due to its high aromatic selectivity (83-85%) and favorable RON (105), although it showed relatively low conversion (∼80%). It was also discovered that the SBB’s high hydrocarbon constituents made it a better feedstock for the production of hydrocarbon fuel than the PBB. Overall, the conversion of animal waste into fuel-range hydrocarbons not only provides an eco-friendly solution for waste management but also holds the potential to enhance energy security by reducing the need for fossil fuels, thereby supporting a more sustainable future.</p>\",\"PeriodicalId\":100015,\"journal\":{\"name\":\"ACS Sustainable Resource Management\",\"volume\":\"2 3\",\"pages\":\"455–462 455–462\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-03-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Sustainable Resource Management\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acssusresmgt.4c00450\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sustainable Resource Management","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acssusresmgt.4c00450","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Valorization of Animal-Waste-Derived Feedstocks through Sustainable Hydrocarbon Fuel Production
The present study reports the first-of-its-kind process for producing sustainable hydrocarbon fuels from novel bio-feedstocks SBB (slaughterhouse-waste biodiesel byproduct) and PBB (poultry-waste biodiesel byproduct) obtained from animal waste oil-based biodiesel. The process demonstrated that the conversion of those feedstocks and hydrocarbon product selectivity varied according to the catalyst and feedstock properties. The Zn/SBZ catalyst possessing the ideal combination of micro-mesopores and acid sites exhibited 100% conversion for those feedstocks to produce liquid products composed of mainly 72-75% aromatics and 25-28% larger non-aromatics (C8–C15 naphthenes and C7–C12 iso-paraffins) with the research octane number (RON) of 100 suitable for sustainable aviation fuel applications. The Zn/Z catalyst only with micropores and predominant acid sites appears to be a suitable catalyst for gasoline production due to its high aromatic selectivity (83-85%) and favorable RON (105), although it showed relatively low conversion (∼80%). It was also discovered that the SBB’s high hydrocarbon constituents made it a better feedstock for the production of hydrocarbon fuel than the PBB. Overall, the conversion of animal waste into fuel-range hydrocarbons not only provides an eco-friendly solution for waste management but also holds the potential to enhance energy security by reducing the need for fossil fuels, thereby supporting a more sustainable future.