Selvamani Arumugam*, Nagabhatla Viswanadham*, Anjan Ray, Anup Prakash Tathod, Arumugam Sivasamy, Kalarical Janardhanan Sreeram and Kamal Singh Koranga, 
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摘要

本研究首次报道了利用新型生物原料 SBB(屠宰场废弃生物柴油副产品)和 PBB(家禽废弃生物柴油副产品)生产可持续碳氢化合物燃料的工艺。该工艺表明,这些原料的转化率和碳氢化合物产品的选择性随催化剂和原料特性的不同而变化。具有微介孔和酸位点理想组合的 Zn/SBZ 催化剂对这些原料的转化率达到 100%,生产出的液体产品主要由 72-75% 的芳烃和 25-28% 的较大非芳烃(C8-C15 环烷和 C7-C12 异链烷烃)组成,研究辛烷值 (RON) 为 100,适合可持续航空燃料应用。仅具有微孔和主要酸性位点的 Zn/Z 催化剂虽然转化率相对较低(∼80%),但由于其较高的芳烃选择性(83-85%)和良好的辛烷值(105),似乎是一种适用于汽油生产的催化剂。研究还发现,与多溴联苯相比,多溴联苯的高碳氢化合物成分使其成为生产碳氢化合物燃料的更好原料。总之,将动物废弃物转化为燃料范围内的碳氢化合物不仅为废弃物管理提供了一种生态友好型解决方案,而且还具有通过减少对化石燃料的需求来提高能源安全的潜力,从而支持更可持续的未来。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Valorization of Animal-Waste-Derived Feedstocks through Sustainable Hydrocarbon Fuel Production

Valorization of Animal-Waste-Derived Feedstocks through Sustainable Hydrocarbon Fuel Production

The present study reports the first-of-its-kind process for producing sustainable hydrocarbon fuels from novel bio-feedstocks SBB (slaughterhouse-waste biodiesel byproduct) and PBB (poultry-waste biodiesel byproduct) obtained from animal waste oil-based biodiesel. The process demonstrated that the conversion of those feedstocks and hydrocarbon product selectivity varied according to the catalyst and feedstock properties. The Zn/SBZ catalyst possessing the ideal combination of micro-mesopores and acid sites exhibited 100% conversion for those feedstocks to produce liquid products composed of mainly 72-75% aromatics and 25-28% larger non-aromatics (C8–C15 naphthenes and C7–C12 iso-paraffins) with the research octane number (RON) of 100 suitable for sustainable aviation fuel applications. The Zn/Z catalyst only with micropores and predominant acid sites appears to be a suitable catalyst for gasoline production due to its high aromatic selectivity (83-85%) and favorable RON (105), although it showed relatively low conversion (∼80%). It was also discovered that the SBB’s high hydrocarbon constituents made it a better feedstock for the production of hydrocarbon fuel than the PBB. Overall, the conversion of animal waste into fuel-range hydrocarbons not only provides an eco-friendly solution for waste management but also holds the potential to enhance energy security by reducing the need for fossil fuels, thereby supporting a more sustainable future.

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