锰-间苯二甲酸乙酯芳烃基金属有机骨架：合成、结构及锂离子电池应用

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2025-02-02 DOI:10.1002/ejic.202400785

Jin-Hua Liu, Dan Liu, Ming-Yue Yu, Li Liu, Yan-Qing Wang, Yan-Fang Huo, Shi-Qi Sun, Sha-Sha Hao

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引用次数: 0

摘要

采用十二羧酸取代间苯二酚[4]芳烃配体(L)，在溶剂热条件下合成了一种新的金属-有机骨架[Mn6(L)(H2O)14]⋅DMA⋅5H2O（定义为Mn-L）。Mn-L具有丰富的羧基结构，作为锂离子电池负极材料具有优异的电化学性能。活化的Mn-L在运行150次后，在200 mA/g时保持598 mAh/g的比容量，在运行350次后，在500 mA/g时保持420 mAh/g的比容量。优异的倍率容量和循环稳定性使Mn-L成为锂离子电池极具前景的负极材料。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Manganese-Resorcin[4]Arene-Based Metal-Organic Framework: Syntheses, Structure and Lithium-Ion Battery Application

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Manganese-Resorcin[4]Arene-Based Metal-Organic Framework: Syntheses, Structure and Lithium-Ion Battery Application

By employing a dodecarboxylic acid substituted resorcin[4]arene ligand (L), a new metal-organic framework (MOF), [Mn₆(L)(H₂O)₁₄] ⋅ DMA ⋅ 5H₂O (defined as Mn-L) has been synthesized under solvothermal conditions. Mn-L shows a 3D framework with abundant carboxyl groups, which result in the excellent electrochemical performance as anode materials in lithium ion batteries (LIBs). The activated Mn-L maintains the specific capacities of 598 mAh/g at 200 mA/g after 150 runs and 420 mAh/g at 500 mA/g after 350 runs. The excellent rate capacity, cyclic stability enable Mn-L to be prospective anode material for LIBs.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.