{"title":"用于可切换式乳液分离的分层结构多孔聚酰胺-酰亚胺膜","authors":"Pengfei Zhang, Bowen Li, Ralph Rolly Gonzales, Kecheng Guan, Zhaohuan Mai, Zhan Li, Mengyang Hu, Liheng Dai, Ping Xu, Keizo Nakagawa, Tomohisa Yoshioka, Hideto Matsuyama","doi":"10.1002/adma.202501092","DOIUrl":null,"url":null,"abstract":"The development of advanced membranes with switchable superwettability has attracted considerable attention for the efficient treatment of oily wastewater. However, challenges persist in designing and fabricating such membranes through straightforward methods. In this study, a novel strategy is presented to design switchable superwettable membranes based on micro/nano-structured porous surfaces and surface chemical composition reorganization. A commercial amphiphilic polymer, polyamide-imide (Torlon), is fabricated into a porous symmetric membrane with a hierarchical surface structure using a one-step non-solvent-induced phase separation method. By leveraging the surface reorganization capability of amphiphilic polymers and the hierarchically porous structure, the resulting membranes demonstrate exceptional superamphiphilicity in air, underwater superoleophobicity, and underoil superhydrophobicity. These properties enable ultrahigh permeance and separation efficiency for oil-in-water, water-in-oil, and crude oil/water emulsions through a gravity-driven process, eliminating the need for external energy. Furthermore, the membranes exhibit excellent antifouling and self-cleaning performance, maintaining stable operation over multiple cycles. This work provides an innovative and scalable approach to next-generation switchable superwettable membranes with broad potential applications in oily wastewater treatment and beyond.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"8 1","pages":""},"PeriodicalIF":27.4000,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hierarchically Structured Porous Polyamide-Imide Membrane for Switchable Emulsion Separation\",\"authors\":\"Pengfei Zhang, Bowen Li, Ralph Rolly Gonzales, Kecheng Guan, Zhaohuan Mai, Zhan Li, Mengyang Hu, Liheng Dai, Ping Xu, Keizo Nakagawa, Tomohisa Yoshioka, Hideto Matsuyama\",\"doi\":\"10.1002/adma.202501092\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The development of advanced membranes with switchable superwettability has attracted considerable attention for the efficient treatment of oily wastewater. However, challenges persist in designing and fabricating such membranes through straightforward methods. In this study, a novel strategy is presented to design switchable superwettable membranes based on micro/nano-structured porous surfaces and surface chemical composition reorganization. A commercial amphiphilic polymer, polyamide-imide (Torlon), is fabricated into a porous symmetric membrane with a hierarchical surface structure using a one-step non-solvent-induced phase separation method. By leveraging the surface reorganization capability of amphiphilic polymers and the hierarchically porous structure, the resulting membranes demonstrate exceptional superamphiphilicity in air, underwater superoleophobicity, and underoil superhydrophobicity. These properties enable ultrahigh permeance and separation efficiency for oil-in-water, water-in-oil, and crude oil/water emulsions through a gravity-driven process, eliminating the need for external energy. Furthermore, the membranes exhibit excellent antifouling and self-cleaning performance, maintaining stable operation over multiple cycles. This work provides an innovative and scalable approach to next-generation switchable superwettable membranes with broad potential applications in oily wastewater treatment and beyond.\",\"PeriodicalId\":114,\"journal\":{\"name\":\"Advanced Materials\",\"volume\":\"8 1\",\"pages\":\"\"},\"PeriodicalIF\":27.4000,\"publicationDate\":\"2025-03-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/adma.202501092\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202501092","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Hierarchically Structured Porous Polyamide-Imide Membrane for Switchable Emulsion Separation
The development of advanced membranes with switchable superwettability has attracted considerable attention for the efficient treatment of oily wastewater. However, challenges persist in designing and fabricating such membranes through straightforward methods. In this study, a novel strategy is presented to design switchable superwettable membranes based on micro/nano-structured porous surfaces and surface chemical composition reorganization. A commercial amphiphilic polymer, polyamide-imide (Torlon), is fabricated into a porous symmetric membrane with a hierarchical surface structure using a one-step non-solvent-induced phase separation method. By leveraging the surface reorganization capability of amphiphilic polymers and the hierarchically porous structure, the resulting membranes demonstrate exceptional superamphiphilicity in air, underwater superoleophobicity, and underoil superhydrophobicity. These properties enable ultrahigh permeance and separation efficiency for oil-in-water, water-in-oil, and crude oil/water emulsions through a gravity-driven process, eliminating the need for external energy. Furthermore, the membranes exhibit excellent antifouling and self-cleaning performance, maintaining stable operation over multiple cycles. This work provides an innovative and scalable approach to next-generation switchable superwettable membranes with broad potential applications in oily wastewater treatment and beyond.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.