微量磷酸钙对胶凝材料水化和孔结构优化的双重动态调节机制

IF 10.9 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY
Lei Wu , Jin Zhong , Zhe Sun , Yan Cao
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引用次数: 0

摘要

本研究探讨了微量磷酸钙(CaP)在硅酸盐水泥水化过程中的调控机制。结果表明,0.001 wt%的CaP通过形成钝化膜延长了诱导期,同时作为成核剂加速了加速阶段的水化速率,从而提高了水化效率和均匀性。CaP提高了C-S-H凝胶的聚合度和均匀性。它调节Ca(OH) 2的形成和分布,促进晶体结构从链状结构到层状或网状结构的可控转变,从而提高稳定性。此外,本研究强调了CaP在新水泥和老水泥体系中的不同作用,并提出了复杂水化过程的多尺度机制。这些发现为CaP在胶凝材料中的应用提供了有价值的理论见解和实践指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Dual dynamic regulation mechanism of trace calcium phosphate on hydration of cementitious materials and optimization of pore structure
This study explores the regulatory mechanisms of trace calcium phosphate (CaP) in the hydration of Portland cement. The results indicate that incorporating 0.001 wt% CaP extends the induction period by forming a passivation film while simultaneously accelerating the hydration rate during the acceleration phase as a nucleation agent, thereby improving hydration efficiency and uniformity. CaP enhances the polymerization degree and homogeneity of C-S-H gel. It modulates the formation and distribution of Ca(OH)₂, facilitating a controlled transition of the crystal structure from a chain-like configuration to layered or network-like forms, thereby enhancing stability. Furthermore, this study highlights the distinct roles of CaP in fresh and aged cement systems and proposes a multi-scale mechanism for complex hydration processes. These findings offer valuable theoretical insights and practical guidance for applying CaP in cementitious materials.
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来源期刊
Cement and Concrete Research
Cement and Concrete Research 工程技术-材料科学:综合
CiteScore
20.90
自引率
12.30%
发文量
318
审稿时长
53 days
期刊介绍: Cement and Concrete Research is dedicated to publishing top-notch research on the materials science and engineering of cement, cement composites, mortars, concrete, and related materials incorporating cement or other mineral binders. The journal prioritizes reporting significant findings in research on the properties and performance of cementitious materials. It also covers novel experimental techniques, the latest analytical and modeling methods, examination and diagnosis of actual cement and concrete structures, and the exploration of potential improvements in materials.
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