溴化胍钝化CsPbBr3量子点及其相关发光二极管的发光和稳定性

IF 3.3 3区 物理与天体物理 Q2 OPTICS
Jianping Huang, Fangfang You, Qing Zhang, Yi Yao, Wenhua Zhang, Faqiang Xu
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引用次数: 0

摘要

全无机钙钛矿CsPbX3 (X = Cl, Br, I)量子点(QDs)由于其优异的光电性能在发光二极管(led)和显示器领域受到了广泛的关注。然而,量子点的固有缺陷和较差的稳定性限制了它们的实际应用。为了解决这些问题,本研究在配体辅助再沉淀法合成CsPbBr3量子点的过程中,引入胍溴(GABr)作为改性剂。XRD和TEM研究表明,GABr的引入在不改变晶体结构的情况下,有效地提高了量子点的结晶度,调整了量子点的形貌。XPS和FTIR结果表明,GA基团不仅通过取代部分长链有机配体辛酸(octac)填补了卤素空位缺陷,而且有效地钝化了不饱和Pb,形成了具有三配体的稳定CsPbBr3量子点,优化了光学性能和稳定性。作为钝化效果的证实,制备了以CsPbBr3量子点为发射层(EMLs)的钙钛矿led器件,钝化后的EML的最大EQE和亮度比原始CsPbBr3量子点器件提高了近2倍,并且电致发光的光谱稳定性明显增强。这项工作为制备高效稳定的CsPbBr3量子点和相关光电器件提供了一种简单的钝化策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhancement of luminescence and stability of CsPbBr3 quantum dots and their related light-emitting diodes through passivation by guanidine bromide
All-inorganic perovskite CsPbX3 (X = Cl, Br, I) quantum dots (QDs) have attracted considerable attention in the fields of light-emitting diodes (LEDs) and displays owing to their excellent photoelectric properties. However, the intrinsic defects and poor stability in QDs limit their practical application. In order to address these problems, this study introduced guanidine bromide (GABr) as modifying agent during the synthesis of CsPbBr3 QDs using the ligand-assisted reprecipitation method. From XRD and TEM studies, the introduction of GABr effectively enhances the crystallinity and adjusts the morphology of QDs without altering the crystal structure. The XPS and FTIR results revealed that the GA group not only fills the halogen vacancy defects by replacing part of the long-chain organic ligand Octanoic acid (OTAc), but also effectively passivate the unsaturated Pb forming a stable CsPbBr3 QD with tri-ligand and optimized optical property and stability. As the confirmation of the passivation effects, the perovskite LEDs (PeLEDs) devices with CsPbBr3 QDs as emission layers (EMLs) were fabricated and the maximum EQE and luminance for the passivated EML are nearly two times higher than that of primeval CsPbBr3 QDs devices, and the spectral stability of electroluminescence is obviously enhanced. This work provides a straightforward passivation strategy for preparing efficient and stable CsPbBr3 QDs and related optoelectronic devices.
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来源期刊
Journal of Luminescence
Journal of Luminescence 物理-光学
CiteScore
6.70
自引率
13.90%
发文量
850
审稿时长
3.8 months
期刊介绍: The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.
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