新型双相Ce0.8Gd0.2O2−δ - Gd1-xCexFe1-yCoyO3复合输氧膜

IF 2.9 Q1 MATERIALS SCIENCE, CERAMICS

Open Ceramics Pub Date : 2025-03-17 DOI:10.1016/j.oceram.2025.100771

Liudmila Fischer , Nawar Haddad , Ke Ran , Stefan Baumann , Doris Sebold , Joachim Mayer , Jürgen Dornseiffer , Arian Nijmeijer , Olivier Guillon , Wilhelm A. Meulenberg

{"title":"新型双相Ce0.8Gd0.2O2−δ - Gd1-xCexFe1-yCoyO3复合输氧膜","authors":"Liudmila Fischer , Nawar Haddad , Ke Ran , Stefan Baumann , Doris Sebold , Joachim Mayer , Jürgen Dornseiffer , Arian Nijmeijer , Olivier Guillon , Wilhelm A. Meulenberg","doi":"10.1016/j.oceram.2025.100771","DOIUrl":null,"url":null,"abstract":"<div><div>Oxygen Transport Membranes with mixed oxygen ionic-electronic conductivity are investigated for in-situ oxygen separation in various processes such as oxy-combustion or catalytic membrane reactors enabling process intensification. Dual-phase composite membranes are of high interest due to the opportunity selecting thermo-chemical stable phases conducting oxygen ions and electrons separately. Recently, we reported a novel composite utilizing a donor doped gadolinium ferrite Gd<sub>0.85</sub>Ce<sub>0.15</sub>Fe<sub>0.75</sub>Co<sub>0.25</sub>O<sub>3</sub> as electronic conductor. Here, the composition of this perovskite system is systematically varied and its structural as well as functional properties are investigated. Moreover, the option of a cobalt-free composition is investigated.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"22 ","pages":"Article 100771"},"PeriodicalIF":2.9000,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane\",\"authors\":\"Liudmila Fischer , Nawar Haddad , Ke Ran , Stefan Baumann , Doris Sebold , Joachim Mayer , Jürgen Dornseiffer , Arian Nijmeijer , Olivier Guillon , Wilhelm A. Meulenberg\",\"doi\":\"10.1016/j.oceram.2025.100771\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Oxygen Transport Membranes with mixed oxygen ionic-electronic conductivity are investigated for in-situ oxygen separation in various processes such as oxy-combustion or catalytic membrane reactors enabling process intensification. Dual-phase composite membranes are of high interest due to the opportunity selecting thermo-chemical stable phases conducting oxygen ions and electrons separately. Recently, we reported a novel composite utilizing a donor doped gadolinium ferrite Gd<sub>0.85</sub>Ce<sub>0.15</sub>Fe<sub>0.75</sub>Co<sub>0.25</sub>O<sub>3</sub> as electronic conductor. Here, the composition of this perovskite system is systematically varied and its structural as well as functional properties are investigated. Moreover, the option of a cobalt-free composition is investigated.</div></div>\",\"PeriodicalId\":34140,\"journal\":{\"name\":\"Open Ceramics\",\"volume\":\"22 \",\"pages\":\"Article 100771\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-03-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Open Ceramics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666539525000380\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Open Ceramics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666539525000380","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}

引用次数: 0

摘要

研究了具有混合氧离子-电子电导率的氧传输膜在各种过程中的原位氧分离，如氧燃烧或催化膜反应器，使过程增强。双相复合膜由于有机会选择热化学稳定相分别导电氧离子和电子而受到高度关注。最近，我们报道了一种利用供体掺杂钆铁氧体Gd0.85Ce0.15Fe0.75Co0.25O3作为电子导体的新型复合材料。本文系统地研究了钙钛矿体系的组成，并对其结构和功能特性进行了研究。此外，还研究了无钴组合物的选择。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane

查看原文本刊更多论文

Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane

Oxygen Transport Membranes with mixed oxygen ionic-electronic conductivity are investigated for in-situ oxygen separation in various processes such as oxy-combustion or catalytic membrane reactors enabling process intensification. Dual-phase composite membranes are of high interest due to the opportunity selecting thermo-chemical stable phases conducting oxygen ions and electrons separately. Recently, we reported a novel composite utilizing a donor doped gadolinium ferrite Gd_0.85Ce_0.15Fe_0.75Co_0.25O₃ as electronic conductor. Here, the composition of this perovskite system is systematically varied and its structural as well as functional properties are investigated. Moreover, the option of a cobalt-free composition is investigated.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊