Yu Liu*, Peng Wang, Xiaoxiao Chen, Yuanhang Zhang, Bo Zhou and Wen Zeng,
{"title":"含水量对含水乙醇/RP-3混合燃料燃烧特性的影响","authors":"Yu Liu*, Peng Wang, Xiaoxiao Chen, Yuanhang Zhang, Bo Zhou and Wen Zeng, ","doi":"10.1021/acsomega.4c1158010.1021/acsomega.4c11580","DOIUrl":null,"url":null,"abstract":"<p >Constant volume chamber (CVC) was adopted to measure the laminar burning velocity (LBV) and Markstein length <i>L</i><sub>b</sub> of hydrous ethanol/RP-3 mixed fuel at initial temperature <i>T</i> = 450 K, initial pressure <i>P</i> = 0.1 MPa, and equivalence ratio ϕ = 0.8–1.4 with hydrous ethanol blending ratio <i>R</i><sub>hydrous ethanol</sub> of 0.2, and the effects of the water content in hydrous ethanol on the LBV and <i>L</i><sub>b</sub> were studied. It is found that with the increased water ratio, the LBV of hydrous ethanol/RP-3 decreases. Kinetic analysis of chemical reactions shows that with the increased water ratio the generations of CH<sub>3</sub> and CH<sub>2</sub> decreased because of more OH radicals participating in the key reactions. Meanwhile, the concentrations of H, O, and OH radicals decreased too, which inhibits the LBV of hydrous ethanol/RP-3. The results also show that with the increased water ratio, the <i>L</i><sub>b</sub> of hydrous ethanol/RP-3 increased, which means that the water content in hydrous ethanol would be beneficial to improve combustion stability. The experimental data obtained in our study will bring theoretical basis and technical support for the use of bioethanol in thermodynamic machinery.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"10 11","pages":"11463–11473 11463–11473"},"PeriodicalIF":4.3000,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c11580","citationCount":"0","resultStr":"{\"title\":\"Effects of Water Content on the Combustion Characteristics of Hydrous Ethanol/RP-3 Mixed Fuel\",\"authors\":\"Yu Liu*, Peng Wang, Xiaoxiao Chen, Yuanhang Zhang, Bo Zhou and Wen Zeng, \",\"doi\":\"10.1021/acsomega.4c1158010.1021/acsomega.4c11580\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Constant volume chamber (CVC) was adopted to measure the laminar burning velocity (LBV) and Markstein length <i>L</i><sub>b</sub> of hydrous ethanol/RP-3 mixed fuel at initial temperature <i>T</i> = 450 K, initial pressure <i>P</i> = 0.1 MPa, and equivalence ratio ϕ = 0.8–1.4 with hydrous ethanol blending ratio <i>R</i><sub>hydrous ethanol</sub> of 0.2, and the effects of the water content in hydrous ethanol on the LBV and <i>L</i><sub>b</sub> were studied. It is found that with the increased water ratio, the LBV of hydrous ethanol/RP-3 decreases. Kinetic analysis of chemical reactions shows that with the increased water ratio the generations of CH<sub>3</sub> and CH<sub>2</sub> decreased because of more OH radicals participating in the key reactions. Meanwhile, the concentrations of H, O, and OH radicals decreased too, which inhibits the LBV of hydrous ethanol/RP-3. The results also show that with the increased water ratio, the <i>L</i><sub>b</sub> of hydrous ethanol/RP-3 increased, which means that the water content in hydrous ethanol would be beneficial to improve combustion stability. The experimental data obtained in our study will bring theoretical basis and technical support for the use of bioethanol in thermodynamic machinery.</p>\",\"PeriodicalId\":22,\"journal\":{\"name\":\"ACS Omega\",\"volume\":\"10 11\",\"pages\":\"11463–11473 11463–11473\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-03-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c11580\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Omega\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsomega.4c11580\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Omega","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsomega.4c11580","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effects of Water Content on the Combustion Characteristics of Hydrous Ethanol/RP-3 Mixed Fuel
Constant volume chamber (CVC) was adopted to measure the laminar burning velocity (LBV) and Markstein length Lb of hydrous ethanol/RP-3 mixed fuel at initial temperature T = 450 K, initial pressure P = 0.1 MPa, and equivalence ratio ϕ = 0.8–1.4 with hydrous ethanol blending ratio Rhydrous ethanol of 0.2, and the effects of the water content in hydrous ethanol on the LBV and Lb were studied. It is found that with the increased water ratio, the LBV of hydrous ethanol/RP-3 decreases. Kinetic analysis of chemical reactions shows that with the increased water ratio the generations of CH3 and CH2 decreased because of more OH radicals participating in the key reactions. Meanwhile, the concentrations of H, O, and OH radicals decreased too, which inhibits the LBV of hydrous ethanol/RP-3. The results also show that with the increased water ratio, the Lb of hydrous ethanol/RP-3 increased, which means that the water content in hydrous ethanol would be beneficial to improve combustion stability. The experimental data obtained in our study will bring theoretical basis and technical support for the use of bioethanol in thermodynamic machinery.
ACS OmegaChemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍:
ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.