含水量对含水乙醇/RP-3混合燃料燃烧特性的影响

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yu Liu*, Peng Wang, Xiaoxiao Chen, Yuanhang Zhang, Bo Zhou and Wen Zeng, 
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引用次数: 0

摘要

在初始温度T = 450 K、初始压力P = 0.1 MPa、等效比φ = 0.8 ~ 1.4、混合比例为0.2时,采用恒容室(CVC)测量了含水乙醇/RP-3混合燃料的层流燃烧速度(LBV)和Markstein长度Lb,并研究了含水乙醇中含水量对LBV和Lb的影响。结果表明,随着水比的增大,有水乙醇/RP-3的LBV减小。化学反应动力学分析表明,随着水比的增加,由于更多OH自由基参与关键反应,CH3和CH2的代数减少。同时,H、O、OH自由基浓度降低,抑制了有水乙醇/RP-3的LBV。结果还表明,随着水比的增加,含水乙醇/RP-3的Lb增大,说明含水乙醇中的水含量有利于提高燃烧稳定性。本研究获得的实验数据将为生物乙醇在热力机械中的应用提供理论依据和技术支持。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effects of Water Content on the Combustion Characteristics of Hydrous Ethanol/RP-3 Mixed Fuel

Constant volume chamber (CVC) was adopted to measure the laminar burning velocity (LBV) and Markstein length Lb of hydrous ethanol/RP-3 mixed fuel at initial temperature T = 450 K, initial pressure P = 0.1 MPa, and equivalence ratio ϕ = 0.8–1.4 with hydrous ethanol blending ratio Rhydrous ethanol of 0.2, and the effects of the water content in hydrous ethanol on the LBV and Lb were studied. It is found that with the increased water ratio, the LBV of hydrous ethanol/RP-3 decreases. Kinetic analysis of chemical reactions shows that with the increased water ratio the generations of CH3 and CH2 decreased because of more OH radicals participating in the key reactions. Meanwhile, the concentrations of H, O, and OH radicals decreased too, which inhibits the LBV of hydrous ethanol/RP-3. The results also show that with the increased water ratio, the Lb of hydrous ethanol/RP-3 increased, which means that the water content in hydrous ethanol would be beneficial to improve combustion stability. The experimental data obtained in our study will bring theoretical basis and technical support for the use of bioethanol in thermodynamic machinery.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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