加速堆肥条件下氨在聚碳酸丙烯酯降解中的作用

IF 1.6 4区化学 Q4 POLYMER SCIENCE

Polymer Science, Series C Pub Date : 2025-02-22 DOI:10.1134/S1811238224600368

E. V. Chernikova, E. S. Trofimchuk, V. V. Mironov, K. V. Efremova, A. V. Plutalova, E. A. Lysenko, A. F. Asachenko, S. A. Rzhevskiy, M. A. Topchiy, I. P. Beletskaya

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引用次数: 0

摘要

以钴和二（三苯基膦）氯化亚胺的salen配合物为介质，以外消旋环氧丙烷和二氧化碳为共聚反应，合成了碳酸单位含量在99%以上的无规聚碳酸酯。对其在加速堆肥条件下的生物降解进行了研究。研究表明，在碳酸丙烯酯堆肥过程中，氨是主要的非生物降解剂。聚合物降解以低速率进行，伴随着分子量的逐渐减少，并产生丙二醇。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Role of Ammonia in Poly(propylene carbonate) Degradation under Accelerated Composting Conditions

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Role of Ammonia in Poly(propylene carbonate) Degradation under Accelerated Composting Conditions

Atactic polycarbonate with the content of carbonate units above 99% has been synthesized by the copolymerization of racemic propylene oxide and carbon dioxide mediated by the salen complex of cobalt and bis(triphenylphosphine)iminium chloride. Its biodegradation under accelerated composting conditions has been studied. It has been shown that ammonia is the main abiotic degradant during the composting of poly(propylene carbonate). Polymer degradation proceeds at a low rate, is accompanied by a gradual decrease in molecular weight, and yields propylene glycol.

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来源期刊

Polymer Science, Series C 工程技术-高分子科学

CiteScore

3.00

自引率

4.50%

发文量

审稿时长

>12 weeks

期刊介绍： Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed