加成聚（5-乙烯基-2-降冰片烯）氢化反应的研究

IF 1.6 4区化学 Q4 POLYMER SCIENCE

Polymer Science, Series C Pub Date : 2024-11-30 DOI:10.1134/S1811238224600319

A. I. Wozniak, A. O. Lunin, A. F. Asachenko, M. A. Topchiy, S. A. Rzhevskiy, E. V. Bermesheva, M. V. Bermeshev

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引用次数: 0

摘要

通过氢化锗反应对加成聚（5-乙烯基-2-降冰片烯）进行改性的研究尚属首次。改性以三乙基锗烷为模型，以 (NHC)Pt 复合物为催化剂。通过优化聚（5-乙烯基-2-降冰片烯）的改性条件，可以合成含有 60-65% 改性单元的高分子量可溶性聚合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Hydrogermylation of Addition Poly(5-vinyl-2-norbornene)

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Hydrogermylation of Addition Poly(5-vinyl-2-norbornene)

The modification of addition poly(5-vinyl-2-norbornene) by the hydrogermylation reaction has been studied for the first time. Modification is carried out using triethylgermane as a model germane and an (NHC)Pt complex, which previously proved to be one of the most efficient catalysts of the hydrosilylation of such objects, as a catalyst. Optimization of the modification conditions of poly(5-vinyl-2-norbornene) allows the synthesis of high molecular weight soluble polymers containing 60‒65% of modified units.

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来源期刊

Polymer Science, Series C 工程技术-高分子科学

CiteScore

3.00

自引率

4.50%

发文量

审稿时长

>12 weeks

期刊介绍： Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed