在 Pt/NiAl2O4 催化剂上进行甘油水相转化

IF 3.5 3区工程技术 Q2 ENGINEERING, CHEMICAL

AIChE Journal Pub Date : 2025-03-22 DOI:10.1002/aic.18828

Lingxiang Huang, Xiaohui Liu, Yanqin Wang, Yongsheng Li, Yong Guo

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引用次数: 0

摘要

甘油是生物柴油生产过程中丰富的副产物，水相重整制氢已被证明是处理甘油的有效方法。本研究利用Pt/NiAl2O4催化剂研究了甘油的APR，旨在开发一种可持续的生物柴油副产品制氢方法。与传统支架相比，NiAl2O4具有更好的热稳定性和抗相变能力。表征技术表明，NiAl2O4载体增强了Pt颗粒的分散性和稳定性，有助于将甘油转化为99.9%的气态产物，寿命超过530小时（仅损失2%）。研究结果表明，Pt/NiAl2O4可有效促进脱氢和水煤气转换反应，从而突出了其在APR生物制氢中的应用潜力。

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Aqueous phase reforming of glycerol over Pt/NiAl2O4 catalyst

Glycerol hydrogen production by aqueous phase reforming (APR) has been shown to be an efficient method of treating glycerol, which is an abundant by-product of biodiesel production. This study investigates the APR of glycerol using a Pt/NiAl₂O₄ catalyst, aiming to develop a sustainable method for hydrogen production from biodiesel byproducts. In comparison with traditional supports, NiAl₂O₄ provides improved thermal stability and resistance to phase transformation. Characterization techniques have revealed that the NiAl₂O₄ support enhances the dispersion and stability of Pt particles, contributing to a glycerol conversion into gaseous products of 99.9% and a lifespan of longer than 530 hours (only 2% loss). Reaction pathways were explored, suggesting that Pt/NiAl₂O₄ effectively promotes both dehydrogenation and water-gas shift reactions, thereby highlighting its potential for APR applications in bio-hydrogen production.

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来源期刊

AIChE Journal 工程技术-工程：化工

CiteScore

7.10

自引率

10.80%

发文量

411

审稿时长

3.6 months

期刊介绍： The AIChE Journal is the premier research monthly in chemical engineering and related fields. This peer-reviewed and broad-based journal reports on the most important and latest technological advances in core areas of chemical engineering as well as in other relevant engineering disciplines. To keep abreast with the progressive outlook of the profession, the Journal has been expanding the scope of its editorial contents to include such fast developing areas as biotechnology, electrochemical engineering, and environmental engineering. The AIChE Journal is indeed the global communications vehicle for the world-renowned researchers to exchange top-notch research findings with one another. Subscribing to the AIChE Journal is like having immediate access to nine topical journals in the field. Articles are categorized according to the following topical areas: Biomolecular Engineering, Bioengineering, Biochemicals, Biofuels, and Food Inorganic Materials: Synthesis and Processing Particle Technology and Fluidization Process Systems Engineering Reaction Engineering, Kinetics and Catalysis Separations: Materials, Devices and Processes Soft Materials: Synthesis, Processing and Products Thermodynamics and Molecular-Scale Phenomena Transport Phenomena and Fluid Mechanics.