壳聚糖衍生的荧光纳米石墨烯存在对单氨基酸和二肽自组装的抑制和调节：胶束介质中染料基白光的产生

IF 3.9 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Langmuir Pub Date : 2025-03-20 DOI:10.1021/acs.langmuir.4c05152

Souvik Layek, Ritwik Hazra, Shreya Mishra, Nilmoni Sarkar

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引用次数: 0

摘要

来自各种生物质和生物废物的荧光碳纳米颗粒非常有用。在这项工作中，我们成功地合成了荧光碳点型纳米氧化石墨烯（nGO）。这些ngo的发射特性在不同的刺激和水二元混合物的存在下被调制。此外，我们已经看到，在阳离子表面活性剂的存在下，ngo表现出聚集诱导的猝灭，直至其胶束前浓度。胶束介质中的两种亲脂性染料与这些ngo结合也能产生优异的白光。此外，荧光成像显示，这些ngo可以抑制l-酪氨酸、l-色氨酸和二苯丙氨酸的自组装，并调节l-蛋氨酸和阿斯巴甜的自组装。因此，这些非政府组织在发光和治疗应用方面具有潜在的用途。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Inhibition and Modulation of the Self-Assembly of Single Amino Acids and Dipeptides in the Presence of Chitosan-Derived Fluorescent Nanographene Oxide: Dye-Based White Light Generation in Micellar Media

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Fluorescent carbon nanoparticles from various biomass and biowastes can be very much useful. In this work, we have successfully synthesized fluorescent carbon dot-type nanographene oxide (nGO). The emission properties of these nGOs were modulated in the presence of different stimuli and aqueous binary mixtures. Further, we have seen that nGOs showed aggregation-induced quenching in the presence of cationic surfactant up to its premicellar concentration. Two lipophilic dyes in micellar media can also generate excellent white light in combination with these nGOs. Further, fluorescence imaging showed that these nGOs could inhibit the usual self-assembly of l-tyrosine, L-tryptophan, and diphenylalanine and modulate the self-assembly of l-methionine and aspartame. Therefore, these nGOs have potential use in light-emitting and therapeutic applications.

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来源期刊

Langmuir 化学-材料科学：综合

CiteScore

6.50

自引率

10.30%

发文量

1464

审稿时长

2.1 months

期刊介绍： Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).