{"title":"咖啡酸在天然生物质吡咯功能化磁性生物炭（PFMB）上的电化学传感研究","authors":"Imen Abidli, Mohamed Bououdina, Latifa Latrous, Adel Megriche","doi":"10.1007/s00604-025-07087-z","DOIUrl":null,"url":null,"abstract":"<div><p>A peanut shell-modified screen-printed carbon electrode (SPE) was developed for the sensing of caffeic acid (CA) in saliva samples using cheap miniaturized analyzer composed of a laptop and an electrochemical workstation. Peanut shells, sourced from abundant biomass residues, were used to fabricate magnetic biochar (MB) and pyrrole-functionalized magnetic biochar (PFMB) with varying pyrrole/Fe ratios through a hydrothermal process. The surface morphology and electrochemical properties of the synthesized PFMB material were analyzed using XRD, FTIR, Raman, SEM, VSM, cyclic voltammetry, and differential pulse voltammetry techniques. The PFMB-modified SPE displayed excellent electrocatalytic response towards CA in a wide linear range from 10 to 600 μM with a low limit of detection of 0.08 μM. The enhanced electrocatalytic response could be ascribed to the synergistic effect of pyrrole-functionalized biochar and Fe<sub>3</sub>O<sub>4</sub> on the newly designed probe. Moreover, the fabricated sensor was successfully utilized for real-time detection of CA in various samples. Quantum chemical modeling was performed to confirm the relevant findings to clarify the structure–activity relationship of CA adsorption on biochar.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":705,"journal":{"name":"Microchimica Acta","volume":"192 4","pages":""},"PeriodicalIF":5.3000,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical sensing of caffeic acid on natural biomass-pyrrole-functionalized magnetic biochar (PFMB) as promising SPE material\",\"authors\":\"Imen Abidli, Mohamed Bououdina, Latifa Latrous, Adel Megriche\",\"doi\":\"10.1007/s00604-025-07087-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A peanut shell-modified screen-printed carbon electrode (SPE) was developed for the sensing of caffeic acid (CA) in saliva samples using cheap miniaturized analyzer composed of a laptop and an electrochemical workstation. Peanut shells, sourced from abundant biomass residues, were used to fabricate magnetic biochar (MB) and pyrrole-functionalized magnetic biochar (PFMB) with varying pyrrole/Fe ratios through a hydrothermal process. The surface morphology and electrochemical properties of the synthesized PFMB material were analyzed using XRD, FTIR, Raman, SEM, VSM, cyclic voltammetry, and differential pulse voltammetry techniques. The PFMB-modified SPE displayed excellent electrocatalytic response towards CA in a wide linear range from 10 to 600 μM with a low limit of detection of 0.08 μM. The enhanced electrocatalytic response could be ascribed to the synergistic effect of pyrrole-functionalized biochar and Fe<sub>3</sub>O<sub>4</sub> on the newly designed probe. Moreover, the fabricated sensor was successfully utilized for real-time detection of CA in various samples. Quantum chemical modeling was performed to confirm the relevant findings to clarify the structure–activity relationship of CA adsorption on biochar.</p><h3>Graphical Abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":705,\"journal\":{\"name\":\"Microchimica Acta\",\"volume\":\"192 4\",\"pages\":\"\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-03-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microchimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00604-025-07087-z\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microchimica Acta","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s00604-025-07087-z","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Electrochemical sensing of caffeic acid on natural biomass-pyrrole-functionalized magnetic biochar (PFMB) as promising SPE material
A peanut shell-modified screen-printed carbon electrode (SPE) was developed for the sensing of caffeic acid (CA) in saliva samples using cheap miniaturized analyzer composed of a laptop and an electrochemical workstation. Peanut shells, sourced from abundant biomass residues, were used to fabricate magnetic biochar (MB) and pyrrole-functionalized magnetic biochar (PFMB) with varying pyrrole/Fe ratios through a hydrothermal process. The surface morphology and electrochemical properties of the synthesized PFMB material were analyzed using XRD, FTIR, Raman, SEM, VSM, cyclic voltammetry, and differential pulse voltammetry techniques. The PFMB-modified SPE displayed excellent electrocatalytic response towards CA in a wide linear range from 10 to 600 μM with a low limit of detection of 0.08 μM. The enhanced electrocatalytic response could be ascribed to the synergistic effect of pyrrole-functionalized biochar and Fe3O4 on the newly designed probe. Moreover, the fabricated sensor was successfully utilized for real-time detection of CA in various samples. Quantum chemical modeling was performed to confirm the relevant findings to clarify the structure–activity relationship of CA adsorption on biochar.
期刊介绍：
As a peer-reviewed journal for analytical sciences and technologies on the micro- and nanoscale, Microchimica Acta has established itself as a premier forum for truly novel approaches in chemical and biochemical analysis. Coverage includes methods and devices that provide expedient solutions to the most contemporary demands in this area. Examples are point-of-care technologies, wearable (bio)sensors, in-vivo-monitoring, micro/nanomotors and materials based on synthetic biology as well as biomedical imaging and targeting.
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