定制Csf/HfC0.76N0.24复合材料,在3000°C下具有卓越的抗烧蚀性

Zheng Peng , Qingsong Ma , Yingjie Cui , Sian Chen , Fuhua Cao , Xiang Xiong
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引用次数: 0

摘要

需要超高温材料来承受高超音速飞行的恶劣空气热化学环境,为超过5马赫的飞行速度奠定基础。在这里,我们提出了一种新型的超高温复合材料,具有优异的抗烧蚀性能,高达3000°C,持续900秒,利用量身定制的超高熔点HfC0.76N0.24基体和短碳纤维增强。该复合材料在3000℃时的耐烧蚀能力是HfC的14倍以上。此外,本研究通过实验结果和理论模拟相结合,首次全面探讨了HfC0.76N0.24基体热氧化演化的内部机制。这些复杂氧化过程的机理细节在化学键和簇演化方面得到阐明,以及它们与合作氧原子和分子的关系。值得注意的是,氮原子不会直接产生气体并从复合材料中逸出,而是与铪原子相互作用形成Hf-C-N-O簇,在烧蚀过程中具有强大的键合能力,从而提高了粘度。这些发现为从微观到宏观尺度的过渡提供了有价值的见解,这将是激励和加速该领域材料发现的范例,并充分利用其在高超声速飞机和航天器应用中的全部潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Tailored Csf/HfC0.76N0.24 composites for superior ablation resistance at 3000°C

Tailored Csf/HfC0.76N0.24 composites for superior ablation resistance at 3000°C
Ultra-high temperature materials are desirable to withstand the severe aero-thermochemical environments of hypersonic flight, paving the groundworks for flight speeds exceeding Mach 5. Here, we present a novel ultra-high temperature composite with superior ablation resistances up to 3000 ​°C for 900 ​s, utilizing a tailored ultra-high melting point HfC0.76N0.24 matrix reinforced with short carbon fibers. The ablation-resistant capability of this composite is over 14 times greater than that of HfC at 3000 ​°C. Furthermore, this research presents the first comprehensive investigation into the internal mechanisms governing thermal oxidation evolution of HfC0.76N0.24 matrix through a combination of experimental results and theoretical simulations. The mechanistic details of these complex oxidation processes are elucidated in terms of chemical bonding and clusters evolutions, along with their relationship to cooperative oxygen atoms and molecules. Notably, nitrogen atoms do not directly generate gas and escape from the composites, rather, they interact with hafnium atoms to form Hf-C-N-O clusters with robust bonding for enhanced viscosity during ablation. These findings provide valuable insights into the transition from micro to macro scales, which will be the paradigm of inspiring and accelerating materials discovery in this field, as well as taking advantage of their full potential in the application of hypersonic aircraft and spacecraft vehicles.
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