Chen-Hao Bao, Lan Li*, Xiao-Fei Wang, Sa-Sa Xia, Xusheng Wang, Cheng-Chao Jin and Zhi Chen*,
{"title":"将多孔框架材料引入光催化生产H2O2","authors":"Chen-Hao Bao, Lan Li*, Xiao-Fei Wang, Sa-Sa Xia, Xusheng Wang, Cheng-Chao Jin and Zhi Chen*, ","doi":"10.1021/acs.nanolett.4c0668010.1021/acs.nanolett.4c06680","DOIUrl":null,"url":null,"abstract":"<p >Photocatalytic H<sub>2</sub>O<sub>2</sub> production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) emerging as highly efficient catalysts. This Review first presents the current research state of porous framework materials in H<sub>2</sub>O<sub>2</sub> photosynthesis, focusing on the progress in H<sub>2</sub>O<sub>2</sub> production across different porous frameworks and mechanism insights gained through advanced techniques. Furthermore, a systematic categorization of material modifications aimed at enhancing the photocatalytic efficiency is provided, linking structural modifications to improved H<sub>2</sub>O<sub>2</sub> production performance. Key factors such as charge carrier separation and transfer, reaction pathways, and material stability are comprehensively analyzed. Finally, the challenges related to stability, scalability, and cost-effectiveness, are discussed alongside opportunities for future advancements. This Review aims to provide insights into understanding and optimizing porous framework materials for efficient and scalable H<sub>2</sub>O<sub>2</sub> photosynthesis.</p>","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"25 11","pages":"4115–4136 4115–4136"},"PeriodicalIF":9.1000,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bringing Porous Framework Materials toward Photocatalytic H2O2 Production\",\"authors\":\"Chen-Hao Bao, Lan Li*, Xiao-Fei Wang, Sa-Sa Xia, Xusheng Wang, Cheng-Chao Jin and Zhi Chen*, \",\"doi\":\"10.1021/acs.nanolett.4c0668010.1021/acs.nanolett.4c06680\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Photocatalytic H<sub>2</sub>O<sub>2</sub> production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) emerging as highly efficient catalysts. This Review first presents the current research state of porous framework materials in H<sub>2</sub>O<sub>2</sub> photosynthesis, focusing on the progress in H<sub>2</sub>O<sub>2</sub> production across different porous frameworks and mechanism insights gained through advanced techniques. Furthermore, a systematic categorization of material modifications aimed at enhancing the photocatalytic efficiency is provided, linking structural modifications to improved H<sub>2</sub>O<sub>2</sub> production performance. Key factors such as charge carrier separation and transfer, reaction pathways, and material stability are comprehensively analyzed. Finally, the challenges related to stability, scalability, and cost-effectiveness, are discussed alongside opportunities for future advancements. This Review aims to provide insights into understanding and optimizing porous framework materials for efficient and scalable H<sub>2</sub>O<sub>2</sub> photosynthesis.</p>\",\"PeriodicalId\":53,\"journal\":{\"name\":\"Nano Letters\",\"volume\":\"25 11\",\"pages\":\"4115–4136 4115–4136\"},\"PeriodicalIF\":9.1000,\"publicationDate\":\"2025-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.nanolett.4c06680\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Letters","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.nanolett.4c06680","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Bringing Porous Framework Materials toward Photocatalytic H2O2 Production
Photocatalytic H2O2 production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) emerging as highly efficient catalysts. This Review first presents the current research state of porous framework materials in H2O2 photosynthesis, focusing on the progress in H2O2 production across different porous frameworks and mechanism insights gained through advanced techniques. Furthermore, a systematic categorization of material modifications aimed at enhancing the photocatalytic efficiency is provided, linking structural modifications to improved H2O2 production performance. Key factors such as charge carrier separation and transfer, reaction pathways, and material stability are comprehensively analyzed. Finally, the challenges related to stability, scalability, and cost-effectiveness, are discussed alongside opportunities for future advancements. This Review aims to provide insights into understanding and optimizing porous framework materials for efficient and scalable H2O2 photosynthesis.
期刊介绍：
Nano Letters serves as a dynamic platform for promptly disseminating original results in fundamental, applied, and emerging research across all facets of nanoscience and nanotechnology. A pivotal criterion for inclusion within Nano Letters is the convergence of at least two different areas or disciplines, ensuring a rich interdisciplinary scope. The journal is dedicated to fostering exploration in diverse areas, including:
- Experimental and theoretical findings on physical, chemical, and biological phenomena at the nanoscale
- Synthesis, characterization, and processing of organic, inorganic, polymer, and hybrid nanomaterials through physical, chemical, and biological methodologies
- Modeling and simulation of synthetic, assembly, and interaction processes
- Realization of integrated nanostructures and nano-engineered devices exhibiting advanced performance
- Applications of nanoscale materials in living and environmental systems
Nano Letters is committed to advancing and showcasing groundbreaking research that intersects various domains, fostering innovation and collaboration in the ever-evolving field of nanoscience and nanotechnology.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
