{"title":"二甲基硫化物在水中的溶解度","authors":"F.-Y. Jou, A. E. Mather and K. A. G. Schmidt*, ","doi":"10.1021/acs.iecr.4c0454310.1021/acs.iecr.4c04543","DOIUrl":null,"url":null,"abstract":"<p >The solubility of dimethyl sulfide in liquid solvents is of considerable interest to the chemical, natural gas, petroleum, food, and pulp and paper industries. There are limited data in the open literature for the solubility of dimethyl sulfide in water at elevated temperatures and pressures. The gaps in the literature data were addressed with new experimental solubility measurements at temperatures in the range (298.15–413.15) K over a wide range of dimethyl sulfide partial pressures. The cubic-plus-association equation of state was used to correlate the new and existing data with a temperature-dependent binary interaction parameter. Henry’s law constants were correlated with temperature over the full temperature range with a Clarke–Glew smoothing equation.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 11","pages":"6180–6187 6180–6187"},"PeriodicalIF":3.9000,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Solubility of Dimethyl Sulfide in Water\",\"authors\":\"F.-Y. Jou, A. E. Mather and K. A. G. Schmidt*, \",\"doi\":\"10.1021/acs.iecr.4c0454310.1021/acs.iecr.4c04543\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The solubility of dimethyl sulfide in liquid solvents is of considerable interest to the chemical, natural gas, petroleum, food, and pulp and paper industries. There are limited data in the open literature for the solubility of dimethyl sulfide in water at elevated temperatures and pressures. The gaps in the literature data were addressed with new experimental solubility measurements at temperatures in the range (298.15–413.15) K over a wide range of dimethyl sulfide partial pressures. The cubic-plus-association equation of state was used to correlate the new and existing data with a temperature-dependent binary interaction parameter. Henry’s law constants were correlated with temperature over the full temperature range with a Clarke–Glew smoothing equation.</p>\",\"PeriodicalId\":39,\"journal\":{\"name\":\"Industrial & Engineering Chemistry Research\",\"volume\":\"64 11\",\"pages\":\"6180–6187 6180–6187\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-03-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial & Engineering Chemistry Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.iecr.4c04543\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial & Engineering Chemistry Research","FirstCategoryId":"5","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.iecr.4c04543","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
The solubility of dimethyl sulfide in liquid solvents is of considerable interest to the chemical, natural gas, petroleum, food, and pulp and paper industries. There are limited data in the open literature for the solubility of dimethyl sulfide in water at elevated temperatures and pressures. The gaps in the literature data were addressed with new experimental solubility measurements at temperatures in the range (298.15–413.15) K over a wide range of dimethyl sulfide partial pressures. The cubic-plus-association equation of state was used to correlate the new and existing data with a temperature-dependent binary interaction parameter. Henry’s law constants were correlated with temperature over the full temperature range with a Clarke–Glew smoothing equation.
期刊介绍：
ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.
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