Leaching profile of per- and polyfluoroalkyl substances from selected e-waste components and potential exposure pathways from discarded components

Improper handling and disposal of Waste Electrical and Electronic Equipment (WEEE) containing PFAS can lead to the release of these substances into the environment. In this study, we have collected and characterized PFAS leaching profiles of selected e-waste components, including keyboards, cables, monitor screens, and circuit boards, and discussed potential PFAS exposure routes during e-waste disposal by landfilling and associated environmental and health risks. The e-waste components were disassembled, separated, sorted, shredded, and grounded, and leaching experiments were conducted for 30 days to elucidate the potential release and distribution of PFAS from the e-waste components into the environment. PFAS were extracted by solid phase extraction and analyzed through liquid chromatography-mass spectrometry (LC-MS/MS) in e-waste leachate samples to investigate their occurrence and composition in the different e-waste components. The leachate from the e-waste components had 21 out of the 40 PFAS analyzed, in which the most predominant and abundant were perfluorobutanoic acid, perfluorohexanoic acid, perfluorooctanoic acid, and perfluorooctanesulfonic acid. The cables had the highest sum of PFAS in the leachate with concentrations up to 465 ng/kg. Mobilization of PFAS from e-waste components deposited in landfills through leachate requires proper management practices to protect the environment and public health.