封面:用lifsi基电解质揭示高能锂离子电池中不锈钢溶解的影响因素(ChemElectroChem 6/2025)

IF 3.5 4区 化学 Q2 ELECTROCHEMISTRY
Marian Cristian Stan, Peng Yan, Gerrit Michael Overhoff, Nick Fehlings, Hyung-Tae Kim, Robert Tobias Hinz, Tjark Thorben Klaus Ingber, Rayan Guerdelli, Christian Wölke, Martin Winter, Gunther Brunklaus, Isidora Cekic-Laskovic
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引用次数: 0

摘要

封面插图描述了使用含有六氟磷酸锂(LiPF6)和锂二(氟磺酰基)亚胺(LiFSI)盐的电解质配方的硬币电池中各种不锈钢(SUS)等级的电化学行为。氯离子(Cl-)作为杂质在LiFSI盐中的存在促进了局部腐蚀,当电池电压接近4.2 V时,导致SUS的点蚀和溶解。这种溶解行为受到多种因素的影响,具体的SUS等级和表面涂层的存在是决定耐腐蚀性的关键因素。更多细节可以在Marian Cristian Stan, Isidora Cekic-Laskovic及其同事的研究文章中找到(DOI:10.1002/celc.202400632)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Front Cover: Unraveling Influential Factors of Stainless-Steel Dissolution in High-Energy Lithium Ion Batteries with LiFSI-Based Electrolytes (ChemElectroChem 6/2025)

Front Cover: Unraveling Influential Factors of Stainless-Steel Dissolution in High-Energy Lithium Ion Batteries with LiFSI-Based Electrolytes (ChemElectroChem 6/2025)

The front cover illustration depicts the electrochemical behavior of various stainless-steel (SUS) grades in coin cells using electrolyte formulations containing lithium hexafluorophosphate (LiPF6) and lithium bis(fluorosulfonyl)imide (LiFSI) salts. The presence of chlorine ions (Cl-) as impurities in the LiFSI salt promotes localized corrosion, leading to pitting and dissolution of SUS when the cell voltage approaches 4.2 V. Such dissolution behavior is influenced by multiple factors, with the specific SUS grade and the presence of surface coatings playing critical roles in determining corrosion resistance. More details can be found in the Research Article by Marian Cristian Stan, Isidora Cekic-Laskovic, and co-workers (DOI:10.1002/celc.202400632.

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来源期刊
ChemElectroChem
ChemElectroChem ELECTROCHEMISTRY-
CiteScore
7.90
自引率
2.50%
发文量
515
审稿时长
1.2 months
期刊介绍: ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
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