{"title":"一种新的双-4-异丙基苯氧基酞菁硅 (IV) 的合成及其对铁 (III) 离子选择性的评估","authors":"Mehmet Salih Ağırtaş, Derya Güngördü Solğun","doi":"10.1002/aoc.70120","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Axial phthalocyanine compound carrying 4-cumyl phenoxy groups was obtained from the reaction of 4-cumyl phenol with silicon phthalocyanine dichloride (SiPcCl<sub>2</sub>). The compound was characterized by <sup>1</sup>H NMR, UV–visible light, FTIR, and mass spectrum. Electronic properties and photochemical properties of the compound were investigated by UV–visible light spectra. Singlet oxygen production capacity for the compound was investigated, and the singlet oxygen production (Φ∆) value was found to be 0.14. The sensor potential of the compound was investigated by UV–visible light spectra against magnesium (II) ions (Mg<sup>2+</sup>), manganese (II) ions (Mn<sup>2+</sup>), sodium (I) ions (Na<sup>+</sup>), nickel (II) ions (Ni<sup>2+</sup>), zinc (II) ions (Zn<sup>2+</sup>), silver (I) ions (Ag<sup>+</sup>), barium (II) ions (Ba<sup>2+</sup>), cadmium (II) ions (Cd<sup>2+</sup>), copper (II) ions (Cu<sup>2+</sup>), cobalt (II) ions (Co<sup>2+</sup>), and iron (III) ions (Fe<sup>3+</sup>). The selective sensitivity of the phthalocyanine compound only to Fe<sup>3+</sup> ions enables the practical analysis of Fe<sup>3+</sup> ions in many environments. This study presents an alternative and practically applicable method for the sensitive determination of Fe<sup>3+</sup> ions, which have widespread adverse effects on the environment, ecosystem and human health.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of a New Bis-4-Cumyl Phenoxy Phthalocyaninato Silicon (IV) and Its Evaluation on Selectivity for Iron (III) Ions\",\"authors\":\"Mehmet Salih Ağırtaş, Derya Güngördü Solğun\",\"doi\":\"10.1002/aoc.70120\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>Axial phthalocyanine compound carrying 4-cumyl phenoxy groups was obtained from the reaction of 4-cumyl phenol with silicon phthalocyanine dichloride (SiPcCl<sub>2</sub>). The compound was characterized by <sup>1</sup>H NMR, UV–visible light, FTIR, and mass spectrum. Electronic properties and photochemical properties of the compound were investigated by UV–visible light spectra. Singlet oxygen production capacity for the compound was investigated, and the singlet oxygen production (Φ∆) value was found to be 0.14. The sensor potential of the compound was investigated by UV–visible light spectra against magnesium (II) ions (Mg<sup>2+</sup>), manganese (II) ions (Mn<sup>2+</sup>), sodium (I) ions (Na<sup>+</sup>), nickel (II) ions (Ni<sup>2+</sup>), zinc (II) ions (Zn<sup>2+</sup>), silver (I) ions (Ag<sup>+</sup>), barium (II) ions (Ba<sup>2+</sup>), cadmium (II) ions (Cd<sup>2+</sup>), copper (II) ions (Cu<sup>2+</sup>), cobalt (II) ions (Co<sup>2+</sup>), and iron (III) ions (Fe<sup>3+</sup>). The selective sensitivity of the phthalocyanine compound only to Fe<sup>3+</sup> ions enables the practical analysis of Fe<sup>3+</sup> ions in many environments. This study presents an alternative and practically applicable method for the sensitive determination of Fe<sup>3+</sup> ions, which have widespread adverse effects on the environment, ecosystem and human health.</p>\\n </div>\",\"PeriodicalId\":8344,\"journal\":{\"name\":\"Applied Organometallic Chemistry\",\"volume\":\"39 4\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2025-03-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70120\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70120","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Synthesis of a New Bis-4-Cumyl Phenoxy Phthalocyaninato Silicon (IV) and Its Evaluation on Selectivity for Iron (III) Ions
Axial phthalocyanine compound carrying 4-cumyl phenoxy groups was obtained from the reaction of 4-cumyl phenol with silicon phthalocyanine dichloride (SiPcCl2). The compound was characterized by 1H NMR, UV–visible light, FTIR, and mass spectrum. Electronic properties and photochemical properties of the compound were investigated by UV–visible light spectra. Singlet oxygen production capacity for the compound was investigated, and the singlet oxygen production (Φ∆) value was found to be 0.14. The sensor potential of the compound was investigated by UV–visible light spectra against magnesium (II) ions (Mg2+), manganese (II) ions (Mn2+), sodium (I) ions (Na+), nickel (II) ions (Ni2+), zinc (II) ions (Zn2+), silver (I) ions (Ag+), barium (II) ions (Ba2+), cadmium (II) ions (Cd2+), copper (II) ions (Cu2+), cobalt (II) ions (Co2+), and iron (III) ions (Fe3+). The selective sensitivity of the phthalocyanine compound only to Fe3+ ions enables the practical analysis of Fe3+ ions in many environments. This study presents an alternative and practically applicable method for the sensitive determination of Fe3+ ions, which have widespread adverse effects on the environment, ecosystem and human health.
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All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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