Yannan Zhu , Nan He , Yumeng Li , Yuxuan Zhu , Gang Qi
{"title":"膦介导的[2+3]/[2+3]多米诺骨牌环化反应:获得环戊烷[3,4]吡咯[1,2-a]吲哚","authors":"Yannan Zhu , Nan He , Yumeng Li , Yuxuan Zhu , Gang Qi","doi":"10.1039/d5cc00618j","DOIUrl":null,"url":null,"abstract":"<div><div>A phosphine-mediated [2+3]/[2+3] domino annulation reaction between indole-derived enones and Morita–Baylis–Hillman (MBH) carbonates was discovered, delivering a series of cyclopentane[3,4]pyrrolo[1,2-<em>a</em>]indoles with up to 87% yield and >20 : 1 dr.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 32","pages":"Pages 5994-5997"},"PeriodicalIF":4.2000,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Phosphine-mediated [2+3]/[2+3] domino annulation reaction: access to cyclopentane[3,4]pyrrolo[1,2-a]indoles†\",\"authors\":\"Yannan Zhu , Nan He , Yumeng Li , Yuxuan Zhu , Gang Qi\",\"doi\":\"10.1039/d5cc00618j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A phosphine-mediated [2+3]/[2+3] domino annulation reaction between indole-derived enones and Morita–Baylis–Hillman (MBH) carbonates was discovered, delivering a series of cyclopentane[3,4]pyrrolo[1,2-<em>a</em>]indoles with up to 87% yield and >20 : 1 dr.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 32\",\"pages\":\"Pages 5994-5997\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-03-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734525005956\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525005956","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Phosphine-mediated [2+3]/[2+3] domino annulation reaction: access to cyclopentane[3,4]pyrrolo[1,2-a]indoles†
A phosphine-mediated [2+3]/[2+3] domino annulation reaction between indole-derived enones and Morita–Baylis–Hillman (MBH) carbonates was discovered, delivering a series of cyclopentane[3,4]pyrrolo[1,2-a]indoles with up to 87% yield and >20 : 1 dr.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.