铑（III）催化衣康酸二甲酯的芳基化：取代苄基琥珀酸酯的易得性

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI:10.1002/ajoc.202400589

Yuito Takatsuji , Prof. Dr. Yoshinosuke Usuki , Prof. Dr. Tetsuya Satoh

引用次数: 0

摘要

在温和的条件下，铑（III）催化衣康酸二甲酯与芳基硼酸的芳基化反应顺利进行，生成苄基琥珀酸酯。本反应提供了一种简单的合成途径，从现成的底物合成苄基琥珀酸酯，由于其生物活性而引起人们的兴趣。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Rhodium(III)‐Catalyzed Arylation of Dimethyl Itaconate: Facile Access to Substituted Benzylidenesuccinates

The rhodium(III)‐catalyzed arylation of dimethyl itaconate with arylboronic acids proceeds smoothly under mild conditions to produce benzylidenesuccinates. The present reaction provides a simple synthesis route to benzylidenesuccinates, which are of interest due to their biological activities, from readily available substrates.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.