聚阳离子蒙脱土纳米粘土皮克林乳液的研制

IF 5.3 2区 地球科学 Q2 CHEMISTRY, PHYSICAL
Iara C. Assunção Dorigon , Maria E. Araújo Pessoa , José C. Queiroz Neto , Debora V.F. Andrade Silva , José E. Soares Filho , Fabiola D. Silva Curbelo
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引用次数: 0

摘要

在全球努力减少对环境的影响和向可持续实践过渡的过程中,皮克林乳液已经成为一种有前途的替代品,因为它不依赖于传统的化学表面活性剂,而传统化学表面活性剂通常是基于石油的,对环境有害。研究了纳米膨润土稳定乳状液的稳定性和流变性能。制备了两种配方,分别含20%和25%的粘土,均添加NaCl。对乳剂的稳定性和流变性进行了评价。结果表明,粘土浓度的增加提高了稳定性,这可能是由于在油水界面形成了强大的机械屏障。流变学上,两种配方都表现出宾厄姆塑性行为,含有25%粘土的乳液表现出更高的表观粘度。这些发现为研究粘土纳米颗粒稳定皮克林乳液的稳定机制提供了新的思路,在工业环境中,特别是在水基钻井液中具有潜在的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Development of Pickering emulsion from polycationic montmorillonite nanoclay

Development of Pickering emulsion from polycationic montmorillonite nanoclay
In the global effort to reduce environmental impacts and transition toward sustainable practices, Pickering emulsions have emerged as a promising alternative due to their independence from conventional chemical surfactants, which are often petroleum-based and environmentally harmful. This study investigates the stability and rheological properties of emulsions stabilized with bentonite nanoparticles. Two formulations were prepared, containing 20 % and 25 % clay, both supplemented with NaCl. The emulsions were evaluated for their stability and rheological behavior. The results revealed that an increased clay concentration improved stability, likely due to the formation of a robust mechanical barrier at the oil-water interface. Rheologically, both formulations exhibited Bingham plastic behavior, with the emulsion containing 25 % clay demonstrating a higher apparent viscosity. These findings offer insights into the stabilizing mechanisms of Pickering emulsions stabilized by clay nanoparticles, with potential applications in industrial settings, particularly in water-based drilling fluids.
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来源期刊
Applied Clay Science
Applied Clay Science 地学-矿物学
CiteScore
10.30
自引率
10.70%
发文量
289
审稿时长
39 days
期刊介绍: Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as: • Synthesis and purification • Structural, crystallographic and mineralogical properties of clays and clay minerals • Thermal properties of clays and clay minerals • Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties • Interaction with water, with polar and apolar molecules • Colloidal properties and rheology • Adsorption, Intercalation, Ionic exchange • Genesis and deposits of clay minerals • Geology and geochemistry of clays • Modification of clays and clay minerals properties by thermal and physical treatments • Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays) • Modification by biological microorganisms. etc...
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