使用丙烯酸环氧化亚麻籽油粘合剂的环保油墨配方:兼顾性能和可持续性

IF 6.5 2区 材料科学 Q1 CHEMISTRY, APPLIED
Manjinder Singh , Brahma Prakash , Rahul Lodhi , Anurag Kulshreshtha , Gaurav Manik
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引用次数: 0

摘要

由于丙烯酸基树脂具有出色的附着力、光泽度和成膜性能,因此印刷油墨中对丙烯酸基树脂粘合剂的需求大幅增长。本研究介绍了丙烯酸环氧化亚麻籽油(AELO)及其聚合物聚(AELO/MMA)的合成过程,它们将作为可持续粘合剂用于纸张印刷应用的油墨配方中。配制的油墨显示出低于 1 μm 的理想粒度和 24.65 和 26.62 mN/m 的表面张力,达到了最佳印刷性能的行业标准。接触角和粘度测量结果表明,这种油墨在纸张基底上的润湿性和转移性都得到了增强,而且至少在一个月内都具有储存稳定性。表面形态分析表明,颜料颗粒分布均匀,有利于快速干燥(4-7 秒),基于聚(AELO/MMA)的油墨显示出卓越的光泽度,表明其具有出色的印刷质量。耐磨性分析表明,基于聚(AELO/MMA)的油墨因磨损而产生的孔隙率变化极小,突出了其在印刷应用中的坚固性。AELO 油墨(0.83)和基于聚 (AELO/MMA) 的油墨(0.85)的颜色强度 ΔE 值均低于 1,这表明人眼无法察觉颜色偏移,并表现出很高的耐摩擦性。此外,光学保留率保持在 90% 以上,同时保留了视觉和功能特性。这项研究为展示和利用亚麻籽油基绿色粘合剂意想不到的潜力铺平了道路,亚麻籽油基绿色粘合剂可有效替代石化衍生树脂,为环保纸张印刷油墨配方提供了一种可持续的高性能替代品。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Eco-friendly ink formulations with acrylated epoxidized linseed oil binders: Balancing performance and sustainability

Eco-friendly ink formulations with acrylated epoxidized linseed oil binders: Balancing performance and sustainability
The demand for acrylic-based resins as binders in printing inks has grown enormously due to their superior adhesion, gloss, and film-forming properties. This study presents the synthesis of acrylated epoxidized linseed oil (AELO) and its polymer, poly (AELO/MMA) to be employed as sustainable binders in ink formulations for paper printing applications. The formulated inks exhibited desirable particle sizes below 1 μm and surface tensions of 24.65 and 26.62 mN/m, meeting the industry standards for optimal printing performance. The contact angle and viscosity measurements confirmed enhanced wettability and transferability on paper substrates, with storage stability for at least one month. Surface morphological analysis revealed a uniform pigment particle distribution, facilitating rapid drying times (4–7 s), with the poly (AELO/MMA)-based ink displaying superior gloss, indicative of excellent print quality. Rub resistance analysis demonstrated that poly (AELO/MMA)-based ink experienced minimal changes in porosity due to abrasion, highlighting its robustness for printing applications. The ΔE values for color strength were desirably below 1 for AELO (0.83) and poly (AELO/MMA)-based inks (0.85), indicating color shifts imperceptible to the human eye and exhibiting high rub resistance. Additionally, optical retention was maintained above 90 %, preserving both visual and functional properties. This study paves the way to demonstrate and utilize the unexpected potential of linseed oil-based green binders, which can effectively replace petrochemical-derived resins, offering a sustainable and performance alternative for eco-friendly paper printing ink formulations.
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来源期刊
Progress in Organic Coatings
Progress in Organic Coatings 工程技术-材料科学:膜
CiteScore
11.40
自引率
15.20%
发文量
577
审稿时长
48 days
期刊介绍: The aim of this international journal is to analyse and publicise the progress and current state of knowledge in the field of organic coatings and related materials. The Editors and the Editorial Board members will solicit both review and research papers from academic and industrial scientists who are actively engaged in research and development or, in the case of review papers, have extensive experience in the subject to be reviewed. Unsolicited manuscripts will be accepted if they meet the journal''s requirements. The journal publishes papers dealing with such subjects as: • Chemical, physical and technological properties of organic coatings and related materials • Problems and methods of preparation, manufacture and application of these materials • Performance, testing and analysis.
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