{"title":"nhc催化heck型C-H叔烷基化构建全碳季中心","authors":"Tinglan Liu , Pan Yue , Chengming Wang","doi":"10.1016/j.tchem.2025.100124","DOIUrl":null,"url":null,"abstract":"<div><div>A variety of alkylated alkenes with all-carbon quaternary centers were regioselectively accessed by Heck-type radical NHC catalysis. The herein-developed methodology may contribute to the efficient and rapid construction of various pharmaceuticals and natural products.</div></div>","PeriodicalId":74918,"journal":{"name":"Tetrahedron chem","volume":"13 ","pages":"Article 100124"},"PeriodicalIF":0.0000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of all-carbon quaternary center by NHC-catalyzed Heck-type C–H tertiary alkylation\",\"authors\":\"Tinglan Liu , Pan Yue , Chengming Wang\",\"doi\":\"10.1016/j.tchem.2025.100124\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A variety of alkylated alkenes with all-carbon quaternary centers were regioselectively accessed by Heck-type radical NHC catalysis. The herein-developed methodology may contribute to the efficient and rapid construction of various pharmaceuticals and natural products.</div></div>\",\"PeriodicalId\":74918,\"journal\":{\"name\":\"Tetrahedron chem\",\"volume\":\"13 \",\"pages\":\"Article 100124\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron chem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666951X25000063\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666951X25000063","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Construction of all-carbon quaternary center by NHC-catalyzed Heck-type C–H tertiary alkylation
A variety of alkylated alkenes with all-carbon quaternary centers were regioselectively accessed by Heck-type radical NHC catalysis. The herein-developed methodology may contribute to the efficient and rapid construction of various pharmaceuticals and natural products.
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