上转换荧光粉LaCaGaO4: Er3+/Yb3+用于光学温度传感和防伪

IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Shengyi Liu , Shang Gao , Duan Gao , Li Wang , Wenbin Song , Han Yin , Ying Zhu , Jingjing Zhang , Qianmiao Yu , Xin Chen
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引用次数: 0

摘要

通过高温固相反应成功合成了LaCaGaO4: Er3+和LaCaGaO4: Er3+/Yb3+荧光粉,并深入研究了它们在980 nm和1550 nm激发下的上转换发光性能。x射线衍射分析证实了材料的相纯度,上转换发光测量显示在可见光和近红外区域发射,主要在530 nm, 550 nm, 670 nm和810 nm,对应Er3+跃迁。机制研究表明,在980 nm激发下,绿色和红色发射都是双光子过程,而在1550 nm激发下,这些发射都是三光子过程。与Yb3+共掺杂增强了发光强度,红绿发射比随着Yb3+浓度的增加而增加。此外,这些材料表现出优异的温度传感能力,热耦合能级的荧光强度比与玻尔兹曼分布表现出良好的一致性。最大灵敏度SAMAX分别为0.00054 K-1 (980 nm激发)和0.00632 K-1 (1550 nm激发),在光学测温、调色和防伪等方面具有很大的应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Up-conversion phosphor LaCaGaO4: Er3+/Yb3+ for the optical temperature sensing and anti-counterfeiting

Up-conversion phosphor LaCaGaO4: Er3+/Yb3+ for the optical temperature sensing and anti-counterfeiting
Successfully synthesized LaCaGaO4: Er3+ and LaCaGaO4: Er3+/Yb3+ phosphors via high-temperature solid-state reactions and thoroughly investigated their up-conversion luminescence properties under 980 nm and 1550 nm excitation. X-ray diffraction analysis confirmed the phase purity of the materials, and up-conversion luminescence measurements demonstrated emissions in the visible and near-infrared regions, primarily at 530 nm, 550 nm, 670 nm, and 810 nm, corresponding to Er3+ transitions. Mechanistic studies revealed that under 980 nm excitation, both green and red emissions are two-photon processes, while under 1550 nm excitation, these emissions are driven by three-photon processes. Co-doping with Yb3+ enhanced luminescence intensity, with an increase in the red-to-green emission ratio as the Yb3+ concentration increased. Furthermore, these materials exhibited excellent temperature sensing capabilities, with fluorescence intensity ratios from thermally coupled energy levels showing good agreement with the Boltzmann distribution. Maximum sensitivities SAMAX of 0.00054 K-1 (980 nm excitation) and 0.00632 K-1 (1550 nm excitation) were achieved, highlighting their potential for applications in optical thermometry, color tuning, and anti-counterfeiting.
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来源期刊
Current Applied Physics
Current Applied Physics 物理-材料科学:综合
CiteScore
4.80
自引率
0.00%
发文量
213
审稿时长
33 days
期刊介绍: Current Applied Physics (Curr. Appl. Phys.) is a monthly published international journal covering all the fields of applied science investigating the physics of the advanced materials for future applications. Other areas covered: Experimental and theoretical aspects of advanced materials and devices dealing with synthesis or structural chemistry, physical and electronic properties, photonics, engineering applications, and uniquely pertinent measurement or analytical techniques. Current Applied Physics, published since 2001, covers physics, chemistry and materials science, including bio-materials, with their engineering aspects. It is a truly interdisciplinary journal opening a forum for scientists of all related fields, a unique point of the journal discriminating it from other worldwide and/or Pacific Rim applied physics journals. Regular research papers, letters and review articles with contents meeting the scope of the journal will be considered for publication after peer review. The Journal is owned by the Korean Physical Society.
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