{"title":"利用可见光/紫外线活化和/或官能化 C-H 键:无金属和光催化剂方法。","authors":"Jitender Bariwal, Erik Van der Eycken","doi":"10.1002/tcr.202400227","DOIUrl":null,"url":null,"abstract":"<p><p>Photosynthesis in plants has inspired photochemical reactions in organic chemistry. Synthetic organic chemists always seek cost-effective, operationally simple, averting the use of toxic and difficult-to-remove metallic catalysts, atom economical, and high product purity in organic reactions. In the last few decades, the use of light as a catalyst in organic reactions has increased exponentially as literature has exploded with examples, particularly by using toxic and expensive metal complexes, photosensitizers like organic dyes, hypervalent iodine, or by using inorganic semiconductors. In this report, we have selected a few interesting examples of photochemical reactions performed without using any metallic catalyst or photosensitizers. These examples use the inherent potential of reactants to utilize light energy to initiate chemical reactions. Our main emphasis is to highlight the structural features in the reactants that can absorb light energy or form an electron donor-acceptor (EDA) complex during the reaction to initiate the photochemical reaction. Considering the high degree of variability in the photochemical reactions, the utmost care has been taken to present the most accurate reaction conditions. A short introductory section on photochemical reactions will act as an anchor that will revolve around the examples discussed and explain the underlying principle of the photochemical reaction mechanism.</p>","PeriodicalId":10046,"journal":{"name":"Chemical record","volume":" ","pages":"e202400227"},"PeriodicalIF":7.0000,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Harnessing Visible/UV Light for the Activation and/or Functionalization of C-H Bonds: Metal- and Photocatalyst-Free Approach.\",\"authors\":\"Jitender Bariwal, Erik Van der Eycken\",\"doi\":\"10.1002/tcr.202400227\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Photosynthesis in plants has inspired photochemical reactions in organic chemistry. Synthetic organic chemists always seek cost-effective, operationally simple, averting the use of toxic and difficult-to-remove metallic catalysts, atom economical, and high product purity in organic reactions. In the last few decades, the use of light as a catalyst in organic reactions has increased exponentially as literature has exploded with examples, particularly by using toxic and expensive metal complexes, photosensitizers like organic dyes, hypervalent iodine, or by using inorganic semiconductors. In this report, we have selected a few interesting examples of photochemical reactions performed without using any metallic catalyst or photosensitizers. These examples use the inherent potential of reactants to utilize light energy to initiate chemical reactions. Our main emphasis is to highlight the structural features in the reactants that can absorb light energy or form an electron donor-acceptor (EDA) complex during the reaction to initiate the photochemical reaction. Considering the high degree of variability in the photochemical reactions, the utmost care has been taken to present the most accurate reaction conditions. A short introductory section on photochemical reactions will act as an anchor that will revolve around the examples discussed and explain the underlying principle of the photochemical reaction mechanism.</p>\",\"PeriodicalId\":10046,\"journal\":{\"name\":\"Chemical record\",\"volume\":\" \",\"pages\":\"e202400227\"},\"PeriodicalIF\":7.0000,\"publicationDate\":\"2025-03-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical record\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/tcr.202400227\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical record","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/tcr.202400227","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Harnessing Visible/UV Light for the Activation and/or Functionalization of C-H Bonds: Metal- and Photocatalyst-Free Approach.
Photosynthesis in plants has inspired photochemical reactions in organic chemistry. Synthetic organic chemists always seek cost-effective, operationally simple, averting the use of toxic and difficult-to-remove metallic catalysts, atom economical, and high product purity in organic reactions. In the last few decades, the use of light as a catalyst in organic reactions has increased exponentially as literature has exploded with examples, particularly by using toxic and expensive metal complexes, photosensitizers like organic dyes, hypervalent iodine, or by using inorganic semiconductors. In this report, we have selected a few interesting examples of photochemical reactions performed without using any metallic catalyst or photosensitizers. These examples use the inherent potential of reactants to utilize light energy to initiate chemical reactions. Our main emphasis is to highlight the structural features in the reactants that can absorb light energy or form an electron donor-acceptor (EDA) complex during the reaction to initiate the photochemical reaction. Considering the high degree of variability in the photochemical reactions, the utmost care has been taken to present the most accurate reaction conditions. A short introductory section on photochemical reactions will act as an anchor that will revolve around the examples discussed and explain the underlying principle of the photochemical reaction mechanism.
期刊介绍:
The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields.
TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.