{"title":"低成本轻质石英纤维增强混合气凝胶纳米复合材料用于高温氧化热防护","authors":"Jinming Wang, Honglin Hu, Yunhua Yang, Junning Li, Qiong Geng, Shipeng Zhu, Jiao Yan","doi":"10.1002/mame.202400291","DOIUrl":null,"url":null,"abstract":"<p>Aerogels are used to achieve lightweight heat insulation in composites. To minimize cost and ensure safety, nanocomposites must be prepared without flammable or explosive solvents at room temperature and ambient-pressure drying. However, fabricating resin aerogel nanocomposites is challenging due to the tendency of porous structures to collapse owing to the complex surface tension in the multiphase system of fibers, resin particles, and solvent. A novel quartz fiber-reinforced hybrid aerogel nanocomposite is successfully prepared using the sol–gel method with self-assembly template polymerization. Two key factors in preventing aerogel collapse include the use of a cationic surfactant as a stabilizer for the initial template and as a surface tension improver during drying. The nanocomposite, with a density of 0.52 g·cm<sup>−3</sup> and thermal conductivity of 0.046 W·m<sup>−1</sup>·K<sup>−1</sup>, exhibited a back-face temperature rise of ≈96.4 °C after a 1500 s arc-wind tunnel ablation test. The maximum ablation retreat is ≈0.26 mm. This novel nanocomposite shows potential for high-temperature protection systems in extreme oxidation environments.</p>","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"310 3","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400291","citationCount":"0","resultStr":"{\"title\":\"Low-Cost Lightweight Quartz Fiber-Reinforced Hybrid Aerogel Nanocomposite for High-Temperature Oxidation Thermal Protection\",\"authors\":\"Jinming Wang, Honglin Hu, Yunhua Yang, Junning Li, Qiong Geng, Shipeng Zhu, Jiao Yan\",\"doi\":\"10.1002/mame.202400291\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Aerogels are used to achieve lightweight heat insulation in composites. To minimize cost and ensure safety, nanocomposites must be prepared without flammable or explosive solvents at room temperature and ambient-pressure drying. However, fabricating resin aerogel nanocomposites is challenging due to the tendency of porous structures to collapse owing to the complex surface tension in the multiphase system of fibers, resin particles, and solvent. A novel quartz fiber-reinforced hybrid aerogel nanocomposite is successfully prepared using the sol–gel method with self-assembly template polymerization. Two key factors in preventing aerogel collapse include the use of a cationic surfactant as a stabilizer for the initial template and as a surface tension improver during drying. The nanocomposite, with a density of 0.52 g·cm<sup>−3</sup> and thermal conductivity of 0.046 W·m<sup>−1</sup>·K<sup>−1</sup>, exhibited a back-face temperature rise of ≈96.4 °C after a 1500 s arc-wind tunnel ablation test. The maximum ablation retreat is ≈0.26 mm. This novel nanocomposite shows potential for high-temperature protection systems in extreme oxidation environments.</p>\",\"PeriodicalId\":18151,\"journal\":{\"name\":\"Macromolecular Materials and Engineering\",\"volume\":\"310 3\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-11-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400291\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Materials and Engineering\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/mame.202400291\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Materials and Engineering","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mame.202400291","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Aerogels are used to achieve lightweight heat insulation in composites. To minimize cost and ensure safety, nanocomposites must be prepared without flammable or explosive solvents at room temperature and ambient-pressure drying. However, fabricating resin aerogel nanocomposites is challenging due to the tendency of porous structures to collapse owing to the complex surface tension in the multiphase system of fibers, resin particles, and solvent. A novel quartz fiber-reinforced hybrid aerogel nanocomposite is successfully prepared using the sol–gel method with self-assembly template polymerization. Two key factors in preventing aerogel collapse include the use of a cationic surfactant as a stabilizer for the initial template and as a surface tension improver during drying. The nanocomposite, with a density of 0.52 g·cm−3 and thermal conductivity of 0.046 W·m−1·K−1, exhibited a back-face temperature rise of ≈96.4 °C after a 1500 s arc-wind tunnel ablation test. The maximum ablation retreat is ≈0.26 mm. This novel nanocomposite shows potential for high-temperature protection systems in extreme oxidation environments.
期刊介绍:
Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications.
Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science.
The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments.
ISSN: 1438-7492 (print). 1439-2054 (online).
Readership:Polymer scientists, chemists, physicists, materials scientists, engineers
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