低成本轻质石英纤维增强混合气凝胶纳米复合材料用于高温氧化热防护

IF 4.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Jinming Wang, Honglin Hu, Yunhua Yang, Junning Li, Qiong Geng, Shipeng Zhu, Jiao Yan
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引用次数: 0

摘要

气凝胶用于复合材料的轻质隔热。为了最大限度地降低成本并确保安全,纳米复合材料的制备必须在室温和常压干燥下无易燃或易爆溶剂。然而,制备树脂气凝胶纳米复合材料具有挑战性,因为纤维、树脂颗粒和溶剂的多相体系中,由于复杂的表面张力,多孔结构容易坍塌。采用自组装模板聚合的溶胶-凝胶法制备了一种新型石英纤维增强杂化气凝胶纳米复合材料。防止气凝胶崩溃的两个关键因素包括使用阳离子表面活性剂作为初始模板的稳定剂和干燥过程中的表面张力改善剂。该纳米复合材料密度为0.52 g·cm−3,导热系数为0.046 W·m−1·K−1,经过1500 s电弧风洞烧蚀试验,其背面温升约为96.4℃。最大烧蚀后退≈0.26 mm。这种新型纳米复合材料显示了在极端氧化环境下高温保护系统的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Low-Cost Lightweight Quartz Fiber-Reinforced Hybrid Aerogel Nanocomposite for High-Temperature Oxidation Thermal Protection

Low-Cost Lightweight Quartz Fiber-Reinforced Hybrid Aerogel Nanocomposite for High-Temperature Oxidation Thermal Protection

Aerogels are used to achieve lightweight heat insulation in composites. To minimize cost and ensure safety, nanocomposites must be prepared without flammable or explosive solvents at room temperature and ambient-pressure drying. However, fabricating resin aerogel nanocomposites is challenging due to the tendency of porous structures to collapse owing to the complex surface tension in the multiphase system of fibers, resin particles, and solvent. A novel quartz fiber-reinforced hybrid aerogel nanocomposite is successfully prepared using the sol–gel method with self-assembly template polymerization. Two key factors in preventing aerogel collapse include the use of a cationic surfactant as a stabilizer for the initial template and as a surface tension improver during drying. The nanocomposite, with a density of 0.52 g·cm−3 and thermal conductivity of 0.046 W·m−1·K−1, exhibited a back-face temperature rise of ≈96.4 °C after a 1500 s arc-wind tunnel ablation test. The maximum ablation retreat is ≈0.26 mm. This novel nanocomposite shows potential for high-temperature protection systems in extreme oxidation environments.

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来源期刊
Macromolecular Materials and Engineering
Macromolecular Materials and Engineering 工程技术-材料科学:综合
CiteScore
7.30
自引率
5.10%
发文量
328
审稿时长
1.6 months
期刊介绍: Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)
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