Marek Bekir , Matthias Schenderlein , Jakob Ruickoldt , Petra Wendler , Joachim Kohlbrecher , Ingo Hoffmann , Martin Reifarth
{"title":"具有螺吡喃基团的光切换表面活性剂——用小角中子散射(SANS)和透射电子显微镜(TEM)揭示胶束结构","authors":"Marek Bekir , Matthias Schenderlein , Jakob Ruickoldt , Petra Wendler , Joachim Kohlbrecher , Ingo Hoffmann , Martin Reifarth","doi":"10.1039/d5cc00577a","DOIUrl":null,"url":null,"abstract":"<div><div>We use SANS and TEM to elucidate the shape of the micelles that a spiropyran (SP) surfactant forms. Being both pH- and photo-switchable to a less surface active merocyanine (MC) form, we find that their micelles are of cylindrical shape in any case, which leads us to conclude that the surfactant always switches to its SP form when micellising.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 30","pages":"Pages 5585-5588"},"PeriodicalIF":4.2000,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A photo-switchable surfactant possessing a spiropyran-moiety in its backbone – unravelling the structure of micelles with small-angle neutron scattering (SANS) and transmission electron microscopy (TEM)†\",\"authors\":\"Marek Bekir , Matthias Schenderlein , Jakob Ruickoldt , Petra Wendler , Joachim Kohlbrecher , Ingo Hoffmann , Martin Reifarth\",\"doi\":\"10.1039/d5cc00577a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>We use SANS and TEM to elucidate the shape of the micelles that a spiropyran (SP) surfactant forms. Being both pH- and photo-switchable to a less surface active merocyanine (MC) form, we find that their micelles are of cylindrical shape in any case, which leads us to conclude that the surfactant always switches to its SP form when micellising.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 30\",\"pages\":\"Pages 5585-5588\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-03-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734525005282\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525005282","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A photo-switchable surfactant possessing a spiropyran-moiety in its backbone – unravelling the structure of micelles with small-angle neutron scattering (SANS) and transmission electron microscopy (TEM)†
We use SANS and TEM to elucidate the shape of the micelles that a spiropyran (SP) surfactant forms. Being both pH- and photo-switchable to a less surface active merocyanine (MC) form, we find that their micelles are of cylindrical shape in any case, which leads us to conclude that the surfactant always switches to its SP form when micellising.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.