六元杂环的光化学多组分合成

IF 2.5 3区 化学 Q2 CHEMISTRY, ORGANIC
Dr. Biplob Borah , Mihir Patat , Dr. L. Raju Chowhan
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引用次数: 0

摘要

尽管在杂环化合物的合成方面取得了有效的进展,但通过结合可见光诱导的自由基化学和多组分反应来获得这些分子是非常苛刻的,也是具有挑战性的。认识到含氧和含氮杂环化合物的重要特征,在自然界中寻找这些有吸引力的分子并开发新的合成策略仍然是合成化学家感兴趣的领域。在这篇小型综述文章中,我们的目标是简要概述最近在基于可见光诱导的光化学多组分反应策略合成以氧和氮为主要杂原子的六元杂环以及含螺旋吲哚分子的六元杂环方面取得的进展。除了在这个有前途的领域解决反应设计和产品开发的关键成功之外,我们还强调了与反应发现相关的主要缺点和挑战,以刺激进一步的后续研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Photochemical Multicomponent Synthesis of Six‐Membered Heterocycles

Photochemical Multicomponent Synthesis of Six‐Membered Heterocycles
Despite the efficient progress achieved in the synthesis of heterocyclic compounds, accessing these molecules by combining both visible lights induced radical chemistry and multicomponent reactions is extremely demanding yet challenging. Recognizing the significant features associated with oxygen‐ and nitrogen‐containing heterocyclic compounds, the search for these attractive molecules in nature and developing new synthetic strategies for synthesizing these molecules remain interesting domain for synthetic chemists. In this mini‐review article, we aim to demonstrate a transitory outline of the recent development achieved in the synthesis of six‐membered heterocycles having oxygen and nitrogen as the major heteroatoms as well as six‐membered heterocycle containing spirooxindole molecules based on visible‐light‐induced photochemical multicomponent reactions strategies. Besides addressing the key success of the reaction design and product developments in this promising area, we have also emphasized the major shortcomings and challenges associated with the reaction discovery in order to stimulate further succeeding investigations.
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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