{"title":"硅丙基功能化4,4′-联吡啶-1,1′-亚硫酸亚硫酸四氯铁酸盐的制备及其在N，N′-烷基二酰胺结构中的应用","authors":"Abdolkarim Zare, Elham Izadi","doi":"10.1007/s11164-024-05494-0","DOIUrl":null,"url":null,"abstract":"<div><p>A novel nanomaterial namely Si-propyl-functionalized 4,4′-bipyridine-1,1ʹ-diium bisulfate tetrachloroferrate anchored to rice husk-derived nano-silica (PBBTRS) was fabricated, and analyses involving EDS (energy-dispersive X-ray spectroscopy), elemental mapping, FE-SEM (field emission scanning electron microscopy), XRD (X-ray diffraction), FT-IR, Raman and inductively coupled plasma-optical emission spectroscopy (ICP-OES) were utilized to corroborate its structure. Thereafter, PBBTRS was applied as a highly efficacious, recoverable and dual-functional catalyst for the construction of <i>N</i>,<i>N</i>′-alkylidene bisamides from aryl aldehydes and primary amides under solvent-free conditions. A valuable improvement in this methodology is performing the reaction under mild conditions (60 °C).</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 3","pages":"1313 - 1328"},"PeriodicalIF":2.8000,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of Si-propyl-functionalized 4,4′-bipyridine-1,1ʹ-diium bisulfate tetrachloroferrate anchored to rice husk-derived nano-silica and its utility for the construction of N,N′-alkylidene bisamides\",\"authors\":\"Abdolkarim Zare, Elham Izadi\",\"doi\":\"10.1007/s11164-024-05494-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A novel nanomaterial namely Si-propyl-functionalized 4,4′-bipyridine-1,1ʹ-diium bisulfate tetrachloroferrate anchored to rice husk-derived nano-silica (PBBTRS) was fabricated, and analyses involving EDS (energy-dispersive X-ray spectroscopy), elemental mapping, FE-SEM (field emission scanning electron microscopy), XRD (X-ray diffraction), FT-IR, Raman and inductively coupled plasma-optical emission spectroscopy (ICP-OES) were utilized to corroborate its structure. Thereafter, PBBTRS was applied as a highly efficacious, recoverable and dual-functional catalyst for the construction of <i>N</i>,<i>N</i>′-alkylidene bisamides from aryl aldehydes and primary amides under solvent-free conditions. A valuable improvement in this methodology is performing the reaction under mild conditions (60 °C).</p><h3>Graphical abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":753,\"journal\":{\"name\":\"Research on Chemical Intermediates\",\"volume\":\"51 3\",\"pages\":\"1313 - 1328\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-01-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Research on Chemical Intermediates\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11164-024-05494-0\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Research on Chemical Intermediates","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11164-024-05494-0","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Fabrication of Si-propyl-functionalized 4,4′-bipyridine-1,1ʹ-diium bisulfate tetrachloroferrate anchored to rice husk-derived nano-silica and its utility for the construction of N,N′-alkylidene bisamides
A novel nanomaterial namely Si-propyl-functionalized 4,4′-bipyridine-1,1ʹ-diium bisulfate tetrachloroferrate anchored to rice husk-derived nano-silica (PBBTRS) was fabricated, and analyses involving EDS (energy-dispersive X-ray spectroscopy), elemental mapping, FE-SEM (field emission scanning electron microscopy), XRD (X-ray diffraction), FT-IR, Raman and inductively coupled plasma-optical emission spectroscopy (ICP-OES) were utilized to corroborate its structure. Thereafter, PBBTRS was applied as a highly efficacious, recoverable and dual-functional catalyst for the construction of N,N′-alkylidene bisamides from aryl aldehydes and primary amides under solvent-free conditions. A valuable improvement in this methodology is performing the reaction under mild conditions (60 °C).
期刊介绍：
Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry.
The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.
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