A continuum, computational study of morphogenesis in lithium intermetallic interfaces in solid state batteries

The design of solid state batteries with lithium anodes is attracting attention for the prospect of high capacity and improved safety over liquid electrolyte systems. The nature of transport with lithium as the current carrier has as a consequence the accretion or stripping away of the anode with every charge–discharge cycle. While this poses challenges from the growth of protrusions (dendrites) to loss of contact, there lurks an opportunity: Morphogenesis at the anode–electrolyte interface layer can be studied, and may ultimately be controlled as a factor in solid state battery design. The accessible interface morphologies, the dynamic paths to them, and mechanisms to control them expand considerably if lithium alloys are introduced in the anode. The thermodynamics and kinetics of lithium intermetallics present principled approaches for morphogenic interface design. In this communication we adopt a computational approach to such an exploration. With phase field models that are parameterized by a combination of first principles atomistic calculations and experiments, we present phenomenological studies of two lithium intermetallics: Li–Mg and Li–Zn. An array of parametric investigations follows on the influence of kinetics, charge–discharge rate, cycling, transport mechanisms and grain structure. The emphasis across these computations is on the dynamic morphogenesis of the intermetallic interface. Specifically, the plating, segregation and smooth distribution of Li, Mg and Zn, the growth and disappearance of voids, evolution of solid electrolyte–anode contact area, and grain boundary structure are investigated. The computational platform is a framework for future studies of morphogenic electrolyte–anode interfaces with more extensive inputs from first principles atomistics and experiments.