IF 2 3区 化学 Q3 BIOCHEMICAL RESEARCH METHODS
Wenqi Wei, Luchen Wei, Shunkun Ouyang, Kangjian Luo, Zhuo Wang, Shiyu Liu, Yongkang Luo, Xiaotao Han
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引用次数: 0

摘要

高场核磁共振实验要求进一步开发绕组结构更实用、磁场均匀性更高的脉冲磁体。介绍了一种基于优化局部分裂结构的高均匀性脉冲磁体的构造方法和试验结果。提出了一种利用间隙垫片对开缝过渡丝进行精密绕制的工艺。利用霍尔探针在32 mT的稳态低磁场下实现了磁场映射,在1厘米直径的球形体积(DSV)上测量到的磁场不均匀性为198±19 ppm。采用核磁共振波谱半峰全宽作为评价脉冲场磁场均匀性的手段。在最佳位置,样品体积为12.6 mm3,低场为7.7 T时,测量到的FWHM为42.2±2.5 ppm。在50 T的高场下,FWHM降低到16.2±0.8 ppm,这在同类报道的脉冲磁体中是优越的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Construction and testing of a high-homogeneity 55 T pulsed magnet for high-field nuclear magnetic resonance measurements

Construction and testing of a high-homogeneity 55 T pulsed magnet for high-field nuclear magnetic resonance measurements
High-field nuclear magnetic resonance (NMR) experiments call for the further development of pulsed magnets with a more practical winding structure and higher magnetic field homogeneity. This study presents the construction method and test results of a high-homogeneity pulsed magnet based on an optimized localized split structure. A winding craft using gap spacers was developed for the precise winding of split-gap transition wires. Magnetic field mapping was achieved in a steady-state low field of 32 mT using a Hall probe, with a measured magnetic field inhomogeneity of 198 ± 19 ppm over 1 cm diameter of spherical volume (DSV). The full-width at half-maximum (FWHM) of NMR spectra was adopted as a means of evaluating the magnetic field homogeneity in the pulsed field. In the optimal position, the measured FWHM is 42.2 ± 2.5 ppm at the low field of 7.7 T over a sample volume of 12.6 mm3. At the high field of 50 T, the FWHM decreases to 16.2 ± 0.8 ppm, which is a superior value achieved in similar reported pulsed magnets.
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来源期刊
CiteScore
3.80
自引率
13.60%
发文量
150
审稿时长
69 days
期刊介绍: The Journal of Magnetic Resonance presents original technical and scientific papers in all aspects of magnetic resonance, including nuclear magnetic resonance spectroscopy (NMR) of solids and liquids, electron spin/paramagnetic resonance (EPR), in vivo magnetic resonance imaging (MRI) and spectroscopy (MRS), nuclear quadrupole resonance (NQR) and magnetic resonance phenomena at nearly zero fields or in combination with optics. The Journal''s main aims include deepening the physical principles underlying all these spectroscopies, publishing significant theoretical and experimental results leading to spectral and spatial progress in these areas, and opening new MR-based applications in chemistry, biology and medicine. The Journal also seeks descriptions of novel apparatuses, new experimental protocols, and new procedures of data analysis and interpretation - including computational and quantum-mechanical methods - capable of advancing MR spectroscopy and imaging.
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