{"title":"一种用于硫化物基全固态锂电池的超稳定预锂化锡阳极。","authors":"Haozhe Geng , Senhe Huang , Zhenyu Zhang , Sheng Han , Rongrong Miao , Jinhui Zhu , Xiaodong Zhuang","doi":"10.1039/d5cc00685f","DOIUrl":null,"url":null,"abstract":"<div><div>A prelithiated Sn (LiSn) anode was developed for sulfide-based all-solid-state Li batteries (ASSLBs), demonstrating high compatibility with Li<sub>6</sub>PS<sub>5</sub>Cl sulfide electrolyte. The LiSn|NCM811 cell achieved 163 mA h g<sup>−1</sup> capacity (0.1C) and 91% retention after 650 cycles (1C). Prelithiation compensated Li loss and mitigated volume expansion, enabling high-performance ASSLBs.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 26","pages":"Pages 5027-5030"},"PeriodicalIF":4.2000,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cc/d5cc00685f?page=search","citationCount":"0","resultStr":"{\"title\":\"An ultra-stable prelithiated Sn anode for sulfide-based all-solid-state Li batteries†\",\"authors\":\"Haozhe Geng , Senhe Huang , Zhenyu Zhang , Sheng Han , Rongrong Miao , Jinhui Zhu , Xiaodong Zhuang\",\"doi\":\"10.1039/d5cc00685f\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A prelithiated Sn (LiSn) anode was developed for sulfide-based all-solid-state Li batteries (ASSLBs), demonstrating high compatibility with Li<sub>6</sub>PS<sub>5</sub>Cl sulfide electrolyte. The LiSn|NCM811 cell achieved 163 mA h g<sup>−1</sup> capacity (0.1C) and 91% retention after 650 cycles (1C). Prelithiation compensated Li loss and mitigated volume expansion, enabling high-performance ASSLBs.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 26\",\"pages\":\"Pages 5027-5030\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-02-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/cc/d5cc00685f?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S135973452500415X\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S135973452500415X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
研究了一种用于硫化物基全固态锂电池(ASSLBs)的预锂化锡(LiSn)阳极,该阳极与Li6PS5Cl硫化物电解质具有良好的相容性。LiSn|NCM811电池达到163 mA h g-1容量(0.1C),在650次循环(1C)后保持91%。预锂化补偿了锂的损失,减轻了体积膨胀,实现了高性能assb。
An ultra-stable prelithiated Sn anode for sulfide-based all-solid-state Li batteries†
A prelithiated Sn (LiSn) anode was developed for sulfide-based all-solid-state Li batteries (ASSLBs), demonstrating high compatibility with Li6PS5Cl sulfide electrolyte. The LiSn|NCM811 cell achieved 163 mA h g−1 capacity (0.1C) and 91% retention after 650 cycles (1C). Prelithiation compensated Li loss and mitigated volume expansion, enabling high-performance ASSLBs.
期刊介绍:
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