烯基聚乙二醇粘合剂:通过氧化腈的室温固化特性、热力学和动力学研究

IF 1 4区 化学 Q4 POLYMER SCIENCE
Yonglin Lei,  Jichuan Huo
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引用次数: 0

摘要

减少高温固化引起的颗粒应力缺陷对推进剂的安全性和性能具有重要意义。本文以聚乙二醇(PEG)为样品,烯丙基缩水甘油酯(AGE)和缩水甘油酯为原料,设计合成了一系列烯丙基聚乙二醇共聚物(APEG)。用对苯二腈和三乙胺原位制备的氧化腈在室温下固化APEG共聚物。讨论了前驱体和固化体系的化学物理性质。结果表明:从peg400到peg4000,拉伸强度、断裂伸长率和硬度呈下降趋势;从peg4000到peg6000,拉伸强度、断裂伸长率和硬度呈上升趋势;随着固化剂含量的增加,APEGs的断裂伸长率降低,抗拉强度增加。对固化体系进行原位IR分析,k = 0.1888 g/(mol min),温度为27℃。对固化体系的初始热分解进行了讨论。计算得到活化能为163.886 kJ/mol,反应级数为0.96 kJ/mol。结果表明,所制备的粘结剂在室温下固化速度快,高温分解时放热量大。基于本研究优异的室温固化性能和较大的放热性能,为解决高温固化带来的问题提供了可行的策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

An Alkenyl Polyethylene Glycol Binder: Room Temperature Curing Properties via Nitrile Oxide, Thermodynamics and Kinetics Study

An Alkenyl Polyethylene Glycol Binder: Room Temperature Curing Properties via Nitrile Oxide, Thermodynamics and Kinetics Study

Reducing the stress defects of grain caused by high temperature curing is of great significance to the safety and performance of propellant. Here, a series of alkenyl polyethylene glycol copolymers (APEG) were designed and synthesized using polyethylene glycol (PEG) samples and allyl glycidyl (AGE) and glycidol as raw materials. The APEG copolymers were cured at room temperature with nitrile oxide prepared in situ from p-benzenedinitrile oxide and triethylamine. The chemico-physical properties of the precursors and cured systems were discussed. The results showed that the tensile strength, the elongation at break and hardness decreased from the case of PEG 400 to the case of PEG 4000 and increased from the case of PEG 4000 to the case of PEG 6000. And the elongation at break of the cured APEGs decreased, the tensile strength increased with the increase of curing agent’s contents. The in situ IR of this cured system was analyzed and k = 0.1888 g/(mol min) at 27°C. The initial thermal decomposition of this cured system was also discussed. The activation energy and reaction order were calculated respectively as 163.886 kJ/mol and 0.96. The results suggested that the prepared binder could be cured rapidly at room temperature and had greater heat release during high temperature decomposition. Based on the excellent room curing performance and great heat release of this work, The APEG copolymers provide a feasible strategy to solve the problems caused by the high temperature curing.

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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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