{"title":"BPFz对无机钙钛矿薄膜和太阳能电池性能的影响","authors":"Shanshan Qi, Pengyang Wang, Hongrui Sun, Yali Liu, Jianlong Chang, Jiahui Li, Ying Zhao, Xiaodan Zhang","doi":"10.1002/solr.202400819","DOIUrl":null,"url":null,"abstract":"<p>Inorganic perovskite exhibits an appropriate bandgap and excellent light and thermal stability, making it an ideal top-cell material for silicon tandem solar cells. However, significant non-radiative recombination losses due to surface defects in inorganic perovskite films, along with phase stability issues in humid environments, restrict the efficiency improvement of inverted inorganic perovskite solar cells (IPSCs). This work reports the preparation of efficient, stable inverted IPSCs by using a multifunctional molecule, bis (pentafluorophenyl) zinc (BPFz), as surface treatment for CsPbI<sub>2.85</sub>Br<sub>0.15</sub> films. After treatment with BPFz, the inorganic perovskite film undergoes secondary grain growth, significantly increasing grain size. Simultaneously, BPFz can passivate undercoordinated Pb<sup>2+</sup>, effectively suppressing nonradiative recombination. Additionally, the fluorinated phenyl group endows the inorganic perovskite film surface with superhydrophobic properties, protecting the perovskite layer from the influence of environmental humidity, while also helping to suppress ion diffusion within the device, enhancing device stability. Ultimately, after surface treatment with BPFz, the efficiency of inverted IPSCs increases from 18.18 to 20.22%, and <i>V</i><sub>OC</sub> increases from 1.169 to 1.231 V, with excellent moisture and thermal stability. This work provides a new approach for the development of high-efficiency and stable IPSCs in the future.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 5","pages":""},"PeriodicalIF":6.0000,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of BPFz on the Performance of Inorganic Perovskite Film and Solar Cells\",\"authors\":\"Shanshan Qi, Pengyang Wang, Hongrui Sun, Yali Liu, Jianlong Chang, Jiahui Li, Ying Zhao, Xiaodan Zhang\",\"doi\":\"10.1002/solr.202400819\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Inorganic perovskite exhibits an appropriate bandgap and excellent light and thermal stability, making it an ideal top-cell material for silicon tandem solar cells. However, significant non-radiative recombination losses due to surface defects in inorganic perovskite films, along with phase stability issues in humid environments, restrict the efficiency improvement of inverted inorganic perovskite solar cells (IPSCs). This work reports the preparation of efficient, stable inverted IPSCs by using a multifunctional molecule, bis (pentafluorophenyl) zinc (BPFz), as surface treatment for CsPbI<sub>2.85</sub>Br<sub>0.15</sub> films. After treatment with BPFz, the inorganic perovskite film undergoes secondary grain growth, significantly increasing grain size. Simultaneously, BPFz can passivate undercoordinated Pb<sup>2+</sup>, effectively suppressing nonradiative recombination. Additionally, the fluorinated phenyl group endows the inorganic perovskite film surface with superhydrophobic properties, protecting the perovskite layer from the influence of environmental humidity, while also helping to suppress ion diffusion within the device, enhancing device stability. Ultimately, after surface treatment with BPFz, the efficiency of inverted IPSCs increases from 18.18 to 20.22%, and <i>V</i><sub>OC</sub> increases from 1.169 to 1.231 V, with excellent moisture and thermal stability. This work provides a new approach for the development of high-efficiency and stable IPSCs in the future.</p>\",\"PeriodicalId\":230,\"journal\":{\"name\":\"Solar RRL\",\"volume\":\"9 5\",\"pages\":\"\"},\"PeriodicalIF\":6.0000,\"publicationDate\":\"2025-01-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar RRL\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/solr.202400819\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar RRL","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/solr.202400819","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Effect of BPFz on the Performance of Inorganic Perovskite Film and Solar Cells
Inorganic perovskite exhibits an appropriate bandgap and excellent light and thermal stability, making it an ideal top-cell material for silicon tandem solar cells. However, significant non-radiative recombination losses due to surface defects in inorganic perovskite films, along with phase stability issues in humid environments, restrict the efficiency improvement of inverted inorganic perovskite solar cells (IPSCs). This work reports the preparation of efficient, stable inverted IPSCs by using a multifunctional molecule, bis (pentafluorophenyl) zinc (BPFz), as surface treatment for CsPbI2.85Br0.15 films. After treatment with BPFz, the inorganic perovskite film undergoes secondary grain growth, significantly increasing grain size. Simultaneously, BPFz can passivate undercoordinated Pb2+, effectively suppressing nonradiative recombination. Additionally, the fluorinated phenyl group endows the inorganic perovskite film surface with superhydrophobic properties, protecting the perovskite layer from the influence of environmental humidity, while also helping to suppress ion diffusion within the device, enhancing device stability. Ultimately, after surface treatment with BPFz, the efficiency of inverted IPSCs increases from 18.18 to 20.22%, and VOC increases from 1.169 to 1.231 V, with excellent moisture and thermal stability. This work provides a new approach for the development of high-efficiency and stable IPSCs in the future.
Solar RRLPhysics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍:
Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.