BPFz对无机钙钛矿薄膜和太阳能电池性能的影响

IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2025-01-19 DOI:10.1002/solr.202400819
Shanshan Qi, Pengyang Wang, Hongrui Sun, Yali Liu, Jianlong Chang, Jiahui Li, Ying Zhao, Xiaodan Zhang
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引用次数: 0

摘要

无机钙钛矿具有合适的带隙和优异的光稳定性和热稳定性,是硅串联太阳能电池的理想顶电池材料。然而,由于无机钙钛矿薄膜表面缺陷造成的显著非辐射复合损失,以及潮湿环境下的相稳定性问题,限制了倒置无机钙钛矿太阳能电池(IPSCs)效率的提高。本文报道了利用多功能分子双(五氟苯基)锌(BPFz)作为CsPbI2.85Br0.15薄膜的表面处理制备高效、稳定的倒置IPSCs。BPFz处理后,无机钙钛矿膜发生二次晶粒生长,晶粒尺寸显著增大。同时,BPFz可以钝化欠配位的Pb2+,有效抑制非辐射重组。此外,氟化苯基赋予无机钙钛矿膜表面超疏水性,保护钙钛矿层免受环境湿度的影响,同时也有助于抑制离子在器件内的扩散,增强器件的稳定性。最终,经过BPFz表面处理后,倒置IPSCs的效率从18.18%提高到20.22%,VOC从1.169提高到1.231 V,具有优异的湿稳定性和热稳定性。本研究为未来高效稳定的诱导多能干细胞的开发提供了新的途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of BPFz on the Performance of Inorganic Perovskite Film and Solar Cells

Effect of BPFz on the Performance of Inorganic Perovskite Film and Solar Cells

Inorganic perovskite exhibits an appropriate bandgap and excellent light and thermal stability, making it an ideal top-cell material for silicon tandem solar cells. However, significant non-radiative recombination losses due to surface defects in inorganic perovskite films, along with phase stability issues in humid environments, restrict the efficiency improvement of inverted inorganic perovskite solar cells (IPSCs). This work reports the preparation of efficient, stable inverted IPSCs by using a multifunctional molecule, bis (pentafluorophenyl) zinc (BPFz), as surface treatment for CsPbI2.85Br0.15 films. After treatment with BPFz, the inorganic perovskite film undergoes secondary grain growth, significantly increasing grain size. Simultaneously, BPFz can passivate undercoordinated Pb2+, effectively suppressing nonradiative recombination. Additionally, the fluorinated phenyl group endows the inorganic perovskite film surface with superhydrophobic properties, protecting the perovskite layer from the influence of environmental humidity, while also helping to suppress ion diffusion within the device, enhancing device stability. Ultimately, after surface treatment with BPFz, the efficiency of inverted IPSCs increases from 18.18 to 20.22%, and VOC increases from 1.169 to 1.231 V, with excellent moisture and thermal stability. This work provides a new approach for the development of high-efficiency and stable IPSCs in the future.

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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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