在防爆区使用 1 mW 激光功率进行癸烯加氢甲酰化过程中的拉曼测量

IF 1.5 4区工程技术 Q3 ENGINEERING, CHEMICAL

Chemie Ingenieur Technik Pub Date : 2024-10-22 DOI:10.1002/cite.202400058

Erik Spoor, Steffen Manser, Dr. Oliver Mandal, Melanie Bruch, Franz-Josef Nagler, Karsten Duch, Dr. Markus Illner, Prof. Dr. Jens-Uwe Repke, Prof. Dr. Matthias Rädle

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引用次数: 0

摘要

改进和调整了定制的拉曼设置，使其能够使用1兆瓦的激光，而不需要光学聚焦元件，从而在Ex区使用。正在考虑的应用是将癸烯氢甲酰化为十一烷，这必须在防爆条件下进行。为了研究分散性混合物，在拉曼探针进行测量的相分离池中进行分离。由此可见，使用高灵敏度的探测器，即使极低的激发功率也可以产生可处理的信号，从而可以应用远低于防爆要求的拉曼测量技术。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Raman Measurements in the Hydroformylation of Decene with Laser Powers of 1 mW in Ex Zones

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Raman Measurements in the Hydroformylation of Decene with Laser Powers of 1 mW in Ex Zones

A custom-made Raman setup is improved and adjusted to allow its use in Ex zones by using a 1-mW laser and no optical focusing elements. The application under consideration is the hydroformylation of decene to undecanal, which must take place under explosion protection. To investigate the dispersive mixture, a separation takes place in a phase separation cell in which the Raman probe performs measurements. It can be shown that, with the use of highly sensitive detectors, even very low excitation powers can lead to a processable signal, and thus the application of Raman measurement technology far below the requirements of explosion protection is possible.

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来源期刊

Chemie Ingenieur Technik 工程技术-工程：化工

CiteScore

3.40

自引率

15.80%

发文量

601

审稿时长

3-6 weeks

期刊介绍： Die Chemie Ingenieur Technik ist die wohl angesehenste deutschsprachige Zeitschrift für Verfahrensingenieure, technische Chemiker, Apparatebauer und Biotechnologen. Als Fachorgan von DECHEMA, GDCh und VDI-GVC gilt sie als das unverzichtbare Forum für den Erfahrungsaustausch zwischen Forschern und Anwendern aus Industrie, Forschung und Entwicklung. Wissenschaftlicher Fortschritt und Praxisnähe: Eine Kombination, die es nur in der CIT gibt!