M. A. Teplonogova, A. A. Kozlova, A. D. Yapryntsev, A. E. Baranchikov, M. M. Khalisov, V. K. Ivanov
{"title":"甘氨酸辅助稀土氧化物形成纳米棒","authors":"M. A. Teplonogova, A. A. Kozlova, A. D. Yapryntsev, A. E. Baranchikov, M. M. Khalisov, V. K. Ivanov","doi":"10.1134/S0036023624603337","DOIUrl":null,"url":null,"abstract":"<p>In this paper, a method was proposed for the synthesis of one-dimensional nanoparticles based on new rare earth (RE) compounds, RE hydroxyglycinates. One-dimensional nanoparticles were obtained by the interaction of RE oxides (Y<sub>2</sub>O<sub>3</sub>, Eu<sub>2</sub>O<sub>3</sub>, Ho<sub>2</sub>O<sub>3</sub>, Er<sub>2</sub>O<sub>3</sub>, Gd<sub>2</sub>O<sub>3</sub>, Sm<sub>2</sub>O<sub>3</sub>) with glycine solutions at the molar ratio NH<sub>2</sub>CH<sub>2</sub>COOH : RE<sub>2</sub>O<sub>3</sub> = 35 : 1 at 60°C. The thickness of nanoparticles was 50–150 nm and the length was 1–5 μm. FT-IR and Raman spectroscopy, thermal analysis and CHN elemental analysis data allowed to establish that the composition of the hydroxyglycinate nanorods is described by the formula Ln(NH<sub>2</sub>CH<sub>2</sub>COO)<sub>1.2</sub>(OH)<sub>1.4</sub>(CO<sub>3</sub>)<sub>0.2</sub>·1.2H<sub>2</sub>O. Based on atomic force microscopy data, the Young’s modulus of one-dimensional europium hydroxyglycinate nanoparticles was determined (~35 GPa) and the lower limit of the shear modulus was estimated (<span>\\( \\gg \\)</span>2.0 GPa).</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 14","pages":"1979 - 1986"},"PeriodicalIF":1.8000,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Glycine-Assisted Formation of Nanorods from Rare Earth Oxides\",\"authors\":\"M. A. Teplonogova, A. A. Kozlova, A. D. Yapryntsev, A. E. Baranchikov, M. M. Khalisov, V. K. Ivanov\",\"doi\":\"10.1134/S0036023624603337\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this paper, a method was proposed for the synthesis of one-dimensional nanoparticles based on new rare earth (RE) compounds, RE hydroxyglycinates. One-dimensional nanoparticles were obtained by the interaction of RE oxides (Y<sub>2</sub>O<sub>3</sub>, Eu<sub>2</sub>O<sub>3</sub>, Ho<sub>2</sub>O<sub>3</sub>, Er<sub>2</sub>O<sub>3</sub>, Gd<sub>2</sub>O<sub>3</sub>, Sm<sub>2</sub>O<sub>3</sub>) with glycine solutions at the molar ratio NH<sub>2</sub>CH<sub>2</sub>COOH : RE<sub>2</sub>O<sub>3</sub> = 35 : 1 at 60°C. The thickness of nanoparticles was 50–150 nm and the length was 1–5 μm. FT-IR and Raman spectroscopy, thermal analysis and CHN elemental analysis data allowed to establish that the composition of the hydroxyglycinate nanorods is described by the formula Ln(NH<sub>2</sub>CH<sub>2</sub>COO)<sub>1.2</sub>(OH)<sub>1.4</sub>(CO<sub>3</sub>)<sub>0.2</sub>·1.2H<sub>2</sub>O. Based on atomic force microscopy data, the Young’s modulus of one-dimensional europium hydroxyglycinate nanoparticles was determined (~35 GPa) and the lower limit of the shear modulus was estimated (<span>\\\\( \\\\gg \\\\)</span>2.0 GPa).</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"69 14\",\"pages\":\"1979 - 1986\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-12-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023624603337\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023624603337","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Glycine-Assisted Formation of Nanorods from Rare Earth Oxides
In this paper, a method was proposed for the synthesis of one-dimensional nanoparticles based on new rare earth (RE) compounds, RE hydroxyglycinates. One-dimensional nanoparticles were obtained by the interaction of RE oxides (Y2O3, Eu2O3, Ho2O3, Er2O3, Gd2O3, Sm2O3) with glycine solutions at the molar ratio NH2CH2COOH : RE2O3 = 35 : 1 at 60°C. The thickness of nanoparticles was 50–150 nm and the length was 1–5 μm. FT-IR and Raman spectroscopy, thermal analysis and CHN elemental analysis data allowed to establish that the composition of the hydroxyglycinate nanorods is described by the formula Ln(NH2CH2COO)1.2(OH)1.4(CO3)0.2·1.2H2O. Based on atomic force microscopy data, the Young’s modulus of one-dimensional europium hydroxyglycinate nanoparticles was determined (~35 GPa) and the lower limit of the shear modulus was estimated (\( \gg \)2.0 GPa).
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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