V. V. Avdeeva, A. S. Kubasov, A. V. Golubev, S. E. Nikiforova, E. A. Malinina, N. T. Kuznetsov
{"title":"偶氮杂环配体（bipy, phen）和高氯近硼酸盐阴离子[BnCln]2 - (n = 10,12)的银(I)配合物","authors":"V. V. Avdeeva, A. S. Kubasov, A. V. Golubev, S. E. Nikiforova, E. A. Malinina, N. T. Kuznetsov","doi":"10.1134/S0036023624602885","DOIUrl":null,"url":null,"abstract":"<p>In this study, the complexation of silver(I) with azaheterocyclic ligands (bipy, phen) in the presence of perchlorinated borate anions, [B<sub>10</sub>Cl<sub>10</sub>]<sup>2–</sup> and [B<sub>12</sub>Cl<sub>12</sub>]<sup>2–</sup>, was investigated in acetonitrile. Complexes with the general formula [Ag<sub>2</sub>L<sub>4</sub>][B<sub><i>n</i></sub>Cl<sub><i>n</i></sub>] (L = bipy, phen; <i>n</i> = 10, 12) were successfully isolated. The final compounds were characterized using elemental analysis and IR spectroscopy. The structures of the [Ag<sub>2</sub>(bipy)<sub>4</sub>][B<sub><i>n</i></sub>Cl<sub><i>n</i></sub>] (<i>n</i> = 10, 12) complexes were elucidated via X-ray diffraction (CCDC nos. 2325088, 2358488). It was determined that the compounds consist of either a binuclear cationic silver(I) complex with azaheterocyclic ligands, [Ag<sub>2</sub>(bipy)<sub>4</sub>]<sup>2+</sup>, or two mononuclear complexes, {[Ag(bipy)<sub>2</sub>]<sub>2</sub>}<sup>2+</sup>, with the boron cluster anions forming the anionic part of both complexes. Additionally, weak argentophilic Ag…Ag interactions were observed within the structures.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 14","pages":"2047 - 2056"},"PeriodicalIF":1.8000,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Silver(I) Complexes with Azaheterocyclic Ligands (bipy, phen) and Perchloro-closo-Borate Anions [BnCln]2– (n = 10, 12)\",\"authors\":\"V. V. Avdeeva, A. S. Kubasov, A. V. Golubev, S. E. Nikiforova, E. A. Malinina, N. T. Kuznetsov\",\"doi\":\"10.1134/S0036023624602885\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this study, the complexation of silver(I) with azaheterocyclic ligands (bipy, phen) in the presence of perchlorinated borate anions, [B<sub>10</sub>Cl<sub>10</sub>]<sup>2–</sup> and [B<sub>12</sub>Cl<sub>12</sub>]<sup>2–</sup>, was investigated in acetonitrile. Complexes with the general formula [Ag<sub>2</sub>L<sub>4</sub>][B<sub><i>n</i></sub>Cl<sub><i>n</i></sub>] (L = bipy, phen; <i>n</i> = 10, 12) were successfully isolated. The final compounds were characterized using elemental analysis and IR spectroscopy. The structures of the [Ag<sub>2</sub>(bipy)<sub>4</sub>][B<sub><i>n</i></sub>Cl<sub><i>n</i></sub>] (<i>n</i> = 10, 12) complexes were elucidated via X-ray diffraction (CCDC nos. 2325088, 2358488). It was determined that the compounds consist of either a binuclear cationic silver(I) complex with azaheterocyclic ligands, [Ag<sub>2</sub>(bipy)<sub>4</sub>]<sup>2+</sup>, or two mononuclear complexes, {[Ag(bipy)<sub>2</sub>]<sub>2</sub>}<sup>2+</sup>, with the boron cluster anions forming the anionic part of both complexes. Additionally, weak argentophilic Ag…Ag interactions were observed within the structures.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"69 14\",\"pages\":\"2047 - 2056\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-11-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023624602885\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023624602885","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Silver(I) Complexes with Azaheterocyclic Ligands (bipy, phen) and Perchloro-closo-Borate Anions [BnCln]2– (n = 10, 12)
In this study, the complexation of silver(I) with azaheterocyclic ligands (bipy, phen) in the presence of perchlorinated borate anions, [B10Cl10]2– and [B12Cl12]2–, was investigated in acetonitrile. Complexes with the general formula [Ag2L4][BnCln] (L = bipy, phen; n = 10, 12) were successfully isolated. The final compounds were characterized using elemental analysis and IR spectroscopy. The structures of the [Ag2(bipy)4][BnCln] (n = 10, 12) complexes were elucidated via X-ray diffraction (CCDC nos. 2325088, 2358488). It was determined that the compounds consist of either a binuclear cationic silver(I) complex with azaheterocyclic ligands, [Ag2(bipy)4]2+, or two mononuclear complexes, {[Ag(bipy)2]2}2+, with the boron cluster anions forming the anionic part of both complexes. Additionally, weak argentophilic Ag…Ag interactions were observed within the structures.
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
![Silver(I) Complexes with Azaheterocyclic Ligands (bipy, phen) and Perchloro-closo-Borate Anions [BnCln]2– (n = 10, 12)](https://img.booksci.cn/booksciimg/2024-11/101301587181772183914.jpg)
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
