A. S. Kubasov, A. V. Golubev, O. M. Stepanova, K. Yu. Zhizhin, N. T. Kuznetsov
{"title":"含羰基的近癸酸阴离子的磺化衍生物","authors":"A. S. Kubasov, A. V. Golubev, O. M. Stepanova, K. Yu. Zhizhin, N. T. Kuznetsov","doi":"10.1134/S0036023624602964","DOIUrl":null,"url":null,"abstract":"<p>This paper presents the synthesis of sulfonium derivatives of the <i>closo</i>-decaborate anion with <i>exo</i>-polyhedral carbonyl groups [B<sub>10</sub>H<sub>9</sub>S(CH<sub>2</sub>C(=O)R)<sub>2</sub>]<sup>–</sup> (R = Me, Ph, <i>p</i>-C<sub>6</sub>H<sub>4</sub>Cl, Nh). The composition and structure have been confirmed by elemental analysis, <sup>11</sup>B, <sup>1</sup>H, and <sup>13</sup>C NMR spectroscopies. Crystal packings and intermolecular interactions for compounds Bu<sub>4</sub>N[2-B<sub>10</sub>H<sub>9</sub>S(CH<sub>2</sub>COMe)<sub>2</sub>] and [Ag(PPh<sub>3</sub>)<sub>4</sub>][2-B<sub>10</sub>H<sub>9</sub>S(CH<sub>2</sub>COC<sub>6</sub>H<sub>4</sub>Cl)<sub>2</sub>] have been studied using single crystal X-ray diffraction and Hirschfeld surface analysis of the anions.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 14","pages":"2065 - 2073"},"PeriodicalIF":1.8000,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sulfonium Derivatives of the closo-Decaborate Anion with Carbonyl Groups\",\"authors\":\"A. S. Kubasov, A. V. Golubev, O. M. Stepanova, K. Yu. Zhizhin, N. T. Kuznetsov\",\"doi\":\"10.1134/S0036023624602964\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This paper presents the synthesis of sulfonium derivatives of the <i>closo</i>-decaborate anion with <i>exo</i>-polyhedral carbonyl groups [B<sub>10</sub>H<sub>9</sub>S(CH<sub>2</sub>C(=O)R)<sub>2</sub>]<sup>–</sup> (R = Me, Ph, <i>p</i>-C<sub>6</sub>H<sub>4</sub>Cl, Nh). The composition and structure have been confirmed by elemental analysis, <sup>11</sup>B, <sup>1</sup>H, and <sup>13</sup>C NMR spectroscopies. Crystal packings and intermolecular interactions for compounds Bu<sub>4</sub>N[2-B<sub>10</sub>H<sub>9</sub>S(CH<sub>2</sub>COMe)<sub>2</sub>] and [Ag(PPh<sub>3</sub>)<sub>4</sub>][2-B<sub>10</sub>H<sub>9</sub>S(CH<sub>2</sub>COC<sub>6</sub>H<sub>4</sub>Cl)<sub>2</sub>] have been studied using single crystal X-ray diffraction and Hirschfeld surface analysis of the anions.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"69 14\",\"pages\":\"2065 - 2073\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023624602964\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023624602964","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Sulfonium Derivatives of the closo-Decaborate Anion with Carbonyl Groups
This paper presents the synthesis of sulfonium derivatives of the closo-decaborate anion with exo-polyhedral carbonyl groups [B10H9S(CH2C(=O)R)2]– (R = Me, Ph, p-C6H4Cl, Nh). The composition and structure have been confirmed by elemental analysis, 11B, 1H, and 13C NMR spectroscopies. Crystal packings and intermolecular interactions for compounds Bu4N[2-B10H9S(CH2COMe)2] and [Ag(PPh3)4][2-B10H9S(CH2COC6H4Cl)2] have been studied using single crystal X-ray diffraction and Hirschfeld surface analysis of the anions.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.