[B10H11] -阴离子与二氰二苯乙烯的反应

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Inorganic Chemistry Pub Date : 2025-01-20 DOI:10.1134/S0036023624603532

N. K. Neumolotov, V. V. Voinova, A. P. Zhdanov, N. A. Selivanov, A. Yu. Bykov, A. A. Yakimanskiy, T. G. Chulkova, A. V. Yakimansky, K. Yu. Zhizhin, N. T. Kuznetsov

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引用次数: 0

摘要

本文主要研究了紧螯合阴离子与一系列取代的二氰二苯乙烯的相互作用。得到了组合物[B10H9R] -的一系列新衍生物，其中R是取代基位于1和10位的菲二代取代基。选择了最佳反应条件。为了提高目标化合物的稳定性，在水-醇介质中，将得到的近癸酸阴离子的腈衍生物与氨反应合成了脒类衍生物。所得化合物的组成和结构采用多核核磁共振波谱、质谱和红外光谱测定。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Reaction of the [B10H11]– Anion with Dicyanostilbenes

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Reaction of the [B10H11]– Anion with Dicyanostilbenes

In this work, the interaction of the closo-decaborate anion with a series of substituted dicyanostilbenes was studied. A range of new derivatives of the composition [B₁₀H₉R]^–, where R is a phenanthrenedicyan substituent with substituents at positions 1 and 10, was obtained. Optimal reaction conditions were selected. To increase the stability of the target compounds, amidine derivatives were synthesized by reacting the obtained nitrile derivatives of the closo-decaborate anion with ammonia in an aqueous-alcoholic medium. The composition and structure of the obtained compounds were determined using multinuclear NMR spectroscopy, mass spectrometry, and IR spectroscopy.

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来源期刊

Russian Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

3.10

自引率

38.10%

发文量

237

审稿时长

3 months

期刊介绍： Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.