柱状[5]芳烃基硅多孔材料的研究进展：从制备到应用

IF 4.8 3区材料科学 Q1 CHEMISTRY, APPLIED

Microporous and Mesoporous Materials Pub Date : 2025-03-04 DOI:10.1016/j.micromeso.2025.113576

Taotao Lu , Hui Li , Yanping Zheng , Lei Shi , Rong Nie , Liang Zhao , Yanxing Qi

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引用次数: 0

摘要

柱状[5]芳烃是一类新型柱状大环宿主，由于其对称的柱状结构、灵活的功能化和独特的主-客体相互作用，在各个领域显示出巨大的潜力。此外，柱状[5]芳烃基功能材料因其独特的拓扑结构和化学结构以及物理化学性质而引起了人们的极大兴趣。本文讨论了柱状b[5]芳烃基硅材料的特殊性能。具体来说，综述了复合柱[5]芳烃基硅材料的制备及其在分子识别、色谱分离、吸附和可控释放（包括pH、电子、温度、离子、气体、多响应控释和渗透释放）方面的应用。最后，展望了柱状b[5]芳烃化学的发展前景。我们期待这篇综述能够为该领域的研究人员提供有价值的参考，并激发与柱状[5]芳烃基材料相关的新发现。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Progress in pillar[5]arene-based silicon porous materials: From preparation to applications

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Progress in pillar[5]arene-based silicon porous materials: From preparation to applications

Pillar[5]arene, a novel class of pillar-shaped macrocyclic hosts, has demonstrated significant potential across diverse fields due to its symmetrical pillar-shaped structures, flexible functionalization, and unique host–guest interactions. Moreover, pillar[5]arene-based functional materials have garnered considerable interest owning to their unique topological and chemical structures, as well as their physicochemical properties. In this review, we discuss the exceptional properties of pillar[5]arene-based silicon materials. Specifically, we summarize the preparation of complex pillar[5]arene-based silicon materials and their applications in molecular recognition, chromatographic separation, adsorption and controllable release (including pH, electron, temperature, ions, gas, multiresponsive controlled release and osmotic release). Finally, we outline the future perspectives of pillar[5]arene chemistry. We anticipate that this review will serve as a valuable reference for researchers in the field and inspire new discoveries related to pillar[5]arene-based materials.

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来源期刊

Microporous and Mesoporous Materials 化学-材料科学：综合

CiteScore

10.70

自引率

5.80%

发文量

649

审稿时长

26 days

期刊介绍： Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal. Topics which are particularly of interest include: All aspects of natural microporous and mesoporous solids The synthesis of crystalline or amorphous porous materials The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials Adsorption (and other separation techniques) using microporous or mesoporous adsorbents Catalysis by microporous and mesoporous materials Host/guest interactions Theoretical chemistry and modelling of host/guest interactions All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.