电催化:实现电子化学未来的前景和作用。

IF 7.5 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Gabriele Centi, Siglinda Perathoner
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引用次数: 0

摘要

电催化是一项至关重要的技术,它将使未来的低碳化工生产和能源超越化石燃料。尽管在这一领域进行了激烈和不断增长的研究,但该领域的潜力在很大程度上尚未开发。我们提供了案例,并讨论了尚未充分研究的新兴可能性,但对于开发这种潜力和实现未来的电子化学是必要的。从定义趋势和设定场景开始,以及澄清电化学和电催化之间的区别,讨论了促进该领域创新的一些要素。其目的是激发讨论和反思,而不是回顾最先进的技术。讨论的方面包括:1)从电催化方法过渡到光电催化方法;2)从空气中制造化学物质的可能性;3)利用阳极和阴极反应,以及串联/成对电催化反应;4)阳极选择性氧化和介导合成的新可能性。讨论了实现电子化学未来的优先事项和策略。加强这些方向的研究,扩展目前仍然过于有限的方法,包括建模和设计,是加速实现分布式未来电子化学的必要努力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Electrocatalysis: Prospects and Role to Enable an E-Chemistry Future

Electrocatalysis: Prospects and Role to Enable an E-Chemistry Future

Electrocatalysis is a crucial technology that will enable future low-carbon chemical production and energy beyond fossil fuels. Notwithstanding the intense and growing research in the area, the potentialities of the field are largely unexplored. We provide case examples and discuss emerging possibilities that have still not been investigated enough but are necessary to exploit this potential and enable future e-chemistry. Starting from defining trends and setting the scene, as well as clarifying the difference between electrochemistry and electrocatalysis, some elements of this vision to foster innovation in the field are discussed. The aim is to stimulate discussion and reflection rather than review the state-of-the-art. Aspects discussed regard i) passing from electro to photoelectrocatalytic approaches, ii) the possibilities of making chemicals from the air, iii) the exploitation of both anodic and cathodic reactions, as well as tandem/paired electrocatalytic reactions, and iv) emerging possibilities for anodic selective oxidation and mediated synthesis. Priorities and strategies to enable an e-chemistry future are discussed. Intensifying research in these directions and extending the still-too-limited current approaches, including in modelling and design, is the necessary effort to accelerate the realisation of a distributed future e-chemistry.

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来源期刊
Chemical record
Chemical record 化学-化学综合
CiteScore
11.00
自引率
3.00%
发文量
188
审稿时长
>12 weeks
期刊介绍: The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
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