{"title":"选择性电催化升级5-羟甲基糠醛制呋喃-2,5-二羧酸的研究进展与展望。","authors":"Lianhua Chen, Yang Liu","doi":"10.1002/tcr.202400238","DOIUrl":null,"url":null,"abstract":"<p>The electrocatalytic upgrading of 5-hydroxymethylfurfural (HMF, 5-(Hydroxymethyl) furan-2-carbaldehyde) has emerged as a renewable and environmentally friendly means for the production of high-value chemicals, with the oxidation product furan-2,5-dicarboxylic acid (FDCA, 2,5-furandicarboxylic acid) possessing economic viability in substituting terephthalic acid in polymer synthesis. This article reviews the recent advancements in the selective electrocatalytic upgrading of HMF to FDCA, including the reaction pathways, mechanisms, as well as activity descriptors of HMF electrocatalytic oxidation reaction (HMFOR), alongside advanced <i>operando</i> characterization techniques. Subsequently, the representative HMFOR catalysts, encompassing noble metal, non-noble metal, transition metal-based catalysts and metal free-based catalysts are presented. Then strategies for regulating HMFOR activity and longevity were introduced, followed by an exploration of the future prospects for the development of HMFOR catalysts.</p>","PeriodicalId":10046,"journal":{"name":"Chemical record","volume":"25 5","pages":""},"PeriodicalIF":7.5000,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Advances and Prospects of Selective Electrocatalytic Upgrading of 5-Hydroxymethylfurfural to Furan-2,5-Dicarboxylic Acid\",\"authors\":\"Lianhua Chen, Yang Liu\",\"doi\":\"10.1002/tcr.202400238\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The electrocatalytic upgrading of 5-hydroxymethylfurfural (HMF, 5-(Hydroxymethyl) furan-2-carbaldehyde) has emerged as a renewable and environmentally friendly means for the production of high-value chemicals, with the oxidation product furan-2,5-dicarboxylic acid (FDCA, 2,5-furandicarboxylic acid) possessing economic viability in substituting terephthalic acid in polymer synthesis. This article reviews the recent advancements in the selective electrocatalytic upgrading of HMF to FDCA, including the reaction pathways, mechanisms, as well as activity descriptors of HMF electrocatalytic oxidation reaction (HMFOR), alongside advanced <i>operando</i> characterization techniques. Subsequently, the representative HMFOR catalysts, encompassing noble metal, non-noble metal, transition metal-based catalysts and metal free-based catalysts are presented. Then strategies for regulating HMFOR activity and longevity were introduced, followed by an exploration of the future prospects for the development of HMFOR catalysts.</p>\",\"PeriodicalId\":10046,\"journal\":{\"name\":\"Chemical record\",\"volume\":\"25 5\",\"pages\":\"\"},\"PeriodicalIF\":7.5000,\"publicationDate\":\"2025-03-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical record\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/tcr.202400238\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical record","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/tcr.202400238","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Advances and Prospects of Selective Electrocatalytic Upgrading of 5-Hydroxymethylfurfural to Furan-2,5-Dicarboxylic Acid
The electrocatalytic upgrading of 5-hydroxymethylfurfural (HMF, 5-(Hydroxymethyl) furan-2-carbaldehyde) has emerged as a renewable and environmentally friendly means for the production of high-value chemicals, with the oxidation product furan-2,5-dicarboxylic acid (FDCA, 2,5-furandicarboxylic acid) possessing economic viability in substituting terephthalic acid in polymer synthesis. This article reviews the recent advancements in the selective electrocatalytic upgrading of HMF to FDCA, including the reaction pathways, mechanisms, as well as activity descriptors of HMF electrocatalytic oxidation reaction (HMFOR), alongside advanced operando characterization techniques. Subsequently, the representative HMFOR catalysts, encompassing noble metal, non-noble metal, transition metal-based catalysts and metal free-based catalysts are presented. Then strategies for regulating HMFOR activity and longevity were introduced, followed by an exploration of the future prospects for the development of HMFOR catalysts.
期刊介绍：
The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields.
TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
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