在环氧树脂中填充磁性BN@Fe3O4核壳颗粒制备导热性和绝缘性能提高的磁性电子封装复合材料

IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC
High Voltage Pub Date : 2025-01-19 DOI:10.1049/hve2.12466
Zeyu You, Ling Weng, Lizhu Guan, Xiaorui Zhang, Zijian Wu, Hao Chen, Wei Zhao
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引用次数: 0

摘要

环氧树脂(EP)作为一种具有优良绝缘性能的树脂材料,已广泛应用于电子、涂料、船舶等领域。但环氧树脂普遍导热性差,限制了其在新一代电子封装领域的应用。为了解决上述关键问题,本研究成功制备了具有正面外导热系数的BN@Fe3O4颗粒,该颗粒具有粗糙表面的核壳结构。六方氮化硼作为一种导热粉末,其易在树脂中结块的缺点得到了改善。通过外加磁场,在基体中构建了三维热传导路径。对BN@Fe3O4粉末及其复合材料的理化性能进行了分析和测试。实验表明,成功制备了导热磁粉BN@Fe3O4。当BN@Fe3O4的填充量达到27.5% vol%时,复合材料的面外导热系数为1.758 W m−1 K−1,为纯EP的982.12%。此时,EP复合材料的力学性能和绝缘性能可以得到与纯EP性能相同数量级的有效保证。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Preparation of magnetic-oriented electronic packaging composite materials with improved thermal conductivity and insulating properties by filling magnetic BN@Fe3O4 core-shell particles into epoxy

Preparation of magnetic-oriented electronic packaging composite materials with improved thermal conductivity and insulating properties by filling magnetic BN@Fe3O4 core-shell particles into epoxy

Epoxy resin (EP), as a resin material with excellent insulation performance, has been widely applied in fields such as electronics, coatings, ships etc. However, epoxy resins generally have poor thermal conductivity, which limits their application in the field of new generation of electronic packaging. To address the key issues mentioned above, the BN@Fe3O4 particles with positive out-of-plane thermal conductivity were successfully prepared in this study, having a core-shell structure with rough surfaces as well. As a thermal conductive powder, the disadvantage of hexagonal boron nitride being easily agglomerated in resin has been improved. By applying an external magnetic field, three-dimensional thermal conduction pathways were constructed in the matrix. The physical and chemical properties of the BN@Fe3O4 powder and its composite materials were analysed and tested. The experiment indicates that the thermal conductive magnetic powder BN@Fe3O4 had been successfully prepared. When the filling amount of BN@Fe3O4 reached 27.5 vol%, the out-of-plane thermal conductivity of the composite material was 1.758 W m−1 K−1, which was 982.12% that of pure EP. At this point, the mechanical behaviour and insulation performance of EP composite materials can be effectively guaranteed at the same order of magnitude as pure EP performance.

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来源期刊
High Voltage
High Voltage Energy-Energy Engineering and Power Technology
CiteScore
9.60
自引率
27.30%
发文量
97
审稿时长
21 weeks
期刊介绍: High Voltage aims to attract original research papers and review articles. The scope covers high-voltage power engineering and high voltage applications, including experimental, computational (including simulation and modelling) and theoretical studies, which include: Electrical Insulation ● Outdoor, indoor, solid, liquid and gas insulation ● Transient voltages and overvoltage protection ● Nano-dielectrics and new insulation materials ● Condition monitoring and maintenance Discharge and plasmas, pulsed power ● Electrical discharge, plasma generation and applications ● Interactions of plasma with surfaces ● Pulsed power science and technology High-field effects ● Computation, measurements of Intensive Electromagnetic Field ● Electromagnetic compatibility ● Biomedical effects ● Environmental effects and protection High Voltage Engineering ● Design problems, testing and measuring techniques ● Equipment development and asset management ● Smart Grid, live line working ● AC/DC power electronics ● UHV power transmission Special Issues. Call for papers: Interface Charging Phenomena for Dielectric Materials - https://digital-library.theiet.org/files/HVE_CFP_ICP.pdf Emerging Materials For High Voltage Applications - https://digital-library.theiet.org/files/HVE_CFP_EMHVA.pdf
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