用腔衰荡光谱法检测SF6和SF6/N2混合物中的特征组分H2S

IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC
High Voltage Pub Date : 2024-12-18 DOI:10.1049/hve2.12508
Anhao Jiang, Chaohai Zhang, Min Zhu, Xiaoxing Zhang
{"title":"用腔衰荡光谱法检测SF6和SF6/N2混合物中的特征组分H2S","authors":"Anhao Jiang,&nbsp;Chaohai Zhang,&nbsp;Min Zhu,&nbsp;Xiaoxing Zhang","doi":"10.1049/hve2.12508","DOIUrl":null,"url":null,"abstract":"<p>A high-sensitivity cavity ring-down spectroscopy gas detection system with integrated optical components and embedded microprocessor units is presented for the detection of hydrogen sulfide (H<sub>2</sub>S) in sulphur hexafluoride (SF<sub>6</sub>) and its mixture with nitrogen (N<sub>2</sub>). The system exploits a periodic laser wavelength modulation to simplify the mode matching. Spectral line profile fitting is used for sample quantitative analysis. To verify the sensitivity and stability of concentration detection, the effect of background gas and temperature on the responses of spectral line broadening and absorption cross-section are investigated. The result deviation caused by variation of background gas can be compensated by the pre-correction of empty cavity ring-down time. It is also found that the implication of temperature on the spectra cannot be ignored. The full width at half maximum and peak value decreased linearly with the increase of temperature, while the baseline is undergoing accelerated growth. Using Allan variance analysis, the limits of detection reach 4.44 × 10<sup>−9</sup> in SF<sub>6</sub> and 2.96 × 10<sup>−9</sup> in N<sub>2</sub> with average time of 67 s. This study provides a meaningful approach for the online detection of characteristic gas in gas insulation equipment.</p>","PeriodicalId":48649,"journal":{"name":"High Voltage","volume":"10 1","pages":"88-94"},"PeriodicalIF":4.4000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/hve2.12508","citationCount":"0","resultStr":"{\"title\":\"Detection of characteristic component H2S in SF6 and SF6/N2 mixture using cavity ring-down spectroscopy\",\"authors\":\"Anhao Jiang,&nbsp;Chaohai Zhang,&nbsp;Min Zhu,&nbsp;Xiaoxing Zhang\",\"doi\":\"10.1049/hve2.12508\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A high-sensitivity cavity ring-down spectroscopy gas detection system with integrated optical components and embedded microprocessor units is presented for the detection of hydrogen sulfide (H<sub>2</sub>S) in sulphur hexafluoride (SF<sub>6</sub>) and its mixture with nitrogen (N<sub>2</sub>). The system exploits a periodic laser wavelength modulation to simplify the mode matching. Spectral line profile fitting is used for sample quantitative analysis. To verify the sensitivity and stability of concentration detection, the effect of background gas and temperature on the responses of spectral line broadening and absorption cross-section are investigated. The result deviation caused by variation of background gas can be compensated by the pre-correction of empty cavity ring-down time. It is also found that the implication of temperature on the spectra cannot be ignored. The full width at half maximum and peak value decreased linearly with the increase of temperature, while the baseline is undergoing accelerated growth. Using Allan variance analysis, the limits of detection reach 4.44 × 10<sup>−9</sup> in SF<sub>6</sub> and 2.96 × 10<sup>−9</sup> in N<sub>2</sub> with average time of 67 s. This study provides a meaningful approach for the online detection of characteristic gas in gas insulation equipment.</p>\",\"PeriodicalId\":48649,\"journal\":{\"name\":\"High Voltage\",\"volume\":\"10 1\",\"pages\":\"88-94\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-12-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1049/hve2.12508\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"High Voltage\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1049/hve2.12508\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Voltage","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1049/hve2.12508","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0

摘要

提出了一种集成光学元件和嵌入式微处理器的高灵敏度腔衰落光谱气体检测系统,用于检测六氟化硫(SF6)及其与氮(N2)混合物中的硫化氢(H2S)。该系统利用周期性激光波长调制来简化模式匹配。采用谱线轮廓拟合进行样品定量分析。为了验证浓度检测的灵敏度和稳定性,研究了背景气体和温度对谱线展宽和吸收截面响应的影响。背景气体变化引起的结果偏差可以通过空腔衰荡时间的预校正来补偿。同时发现温度对光谱的影响是不可忽视的。半峰全宽和峰宽随温度的升高呈线性下降,而基线则呈加速增长趋势。Allan方差分析表明,SF6和N2的检测限分别为4.44 × 10−9和2.96 × 10−9,平均检测时间为67 s。本研究为气体绝缘设备特征气体的在线检测提供了一种有意义的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Detection of characteristic component H2S in SF6 and SF6/N2 mixture using cavity ring-down spectroscopy

Detection of characteristic component H2S in SF6 and SF6/N2 mixture using cavity ring-down spectroscopy

A high-sensitivity cavity ring-down spectroscopy gas detection system with integrated optical components and embedded microprocessor units is presented for the detection of hydrogen sulfide (H2S) in sulphur hexafluoride (SF6) and its mixture with nitrogen (N2). The system exploits a periodic laser wavelength modulation to simplify the mode matching. Spectral line profile fitting is used for sample quantitative analysis. To verify the sensitivity and stability of concentration detection, the effect of background gas and temperature on the responses of spectral line broadening and absorption cross-section are investigated. The result deviation caused by variation of background gas can be compensated by the pre-correction of empty cavity ring-down time. It is also found that the implication of temperature on the spectra cannot be ignored. The full width at half maximum and peak value decreased linearly with the increase of temperature, while the baseline is undergoing accelerated growth. Using Allan variance analysis, the limits of detection reach 4.44 × 10−9 in SF6 and 2.96 × 10−9 in N2 with average time of 67 s. This study provides a meaningful approach for the online detection of characteristic gas in gas insulation equipment.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
High Voltage
High Voltage Energy-Energy Engineering and Power Technology
CiteScore
9.60
自引率
27.30%
发文量
97
审稿时长
21 weeks
期刊介绍: High Voltage aims to attract original research papers and review articles. The scope covers high-voltage power engineering and high voltage applications, including experimental, computational (including simulation and modelling) and theoretical studies, which include: Electrical Insulation ● Outdoor, indoor, solid, liquid and gas insulation ● Transient voltages and overvoltage protection ● Nano-dielectrics and new insulation materials ● Condition monitoring and maintenance Discharge and plasmas, pulsed power ● Electrical discharge, plasma generation and applications ● Interactions of plasma with surfaces ● Pulsed power science and technology High-field effects ● Computation, measurements of Intensive Electromagnetic Field ● Electromagnetic compatibility ● Biomedical effects ● Environmental effects and protection High Voltage Engineering ● Design problems, testing and measuring techniques ● Equipment development and asset management ● Smart Grid, live line working ● AC/DC power electronics ● UHV power transmission Special Issues. Call for papers: Interface Charging Phenomena for Dielectric Materials - https://digital-library.theiet.org/files/HVE_CFP_ICP.pdf Emerging Materials For High Voltage Applications - https://digital-library.theiet.org/files/HVE_CFP_EMHVA.pdf
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信