{"title":"通过 C (sp2)-X 键官能化将二氧化碳固定为有用的芳香族羧酸","authors":"Youwen Chen, Meihua Chen, Xinyu Li, Xinhua Xu, Shuang-Feng Yin, Renhua Qiu","doi":"10.1007/s41061-025-00496-x","DOIUrl":null,"url":null,"abstract":"<div><p>Carbon dioxide (CO<sub>2</sub>) is an abundant and readily available carbon source. Its transformation into high-added-value chemicals is a beneficial strategy, which mitigates greenhouse gas emissions and provides new raw material sources for the chemical industry. Among these chemicals, the aromatic carboxylic acids and derivatives have broad applications in medicine, pesticides, and materials science. Therefore, the carboxylation of C(sp<sup>2</sup>)-X (X = metal, halide, H, O, or S) bonds with CO<sub>2</sub> to efficiently construct aromatic carboxylic acids and their derivatives is a synthetic strategy of significance. This review highlights the recent progress in constructing carboxylic acids and derivatives through the carboxylation of C(sp<sup>2</sup>)-X bonds with CO<sub>2</sub> including literature published from 2000 to December 2024.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":802,"journal":{"name":"Topics in Current Chemistry","volume":"383 1","pages":""},"PeriodicalIF":8.6000,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CO2 Fixation into Useful Aromatic Carboxylic Acids via C (sp2)–X Bonds Functionalization\",\"authors\":\"Youwen Chen, Meihua Chen, Xinyu Li, Xinhua Xu, Shuang-Feng Yin, Renhua Qiu\",\"doi\":\"10.1007/s41061-025-00496-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Carbon dioxide (CO<sub>2</sub>) is an abundant and readily available carbon source. Its transformation into high-added-value chemicals is a beneficial strategy, which mitigates greenhouse gas emissions and provides new raw material sources for the chemical industry. Among these chemicals, the aromatic carboxylic acids and derivatives have broad applications in medicine, pesticides, and materials science. Therefore, the carboxylation of C(sp<sup>2</sup>)-X (X = metal, halide, H, O, or S) bonds with CO<sub>2</sub> to efficiently construct aromatic carboxylic acids and their derivatives is a synthetic strategy of significance. This review highlights the recent progress in constructing carboxylic acids and derivatives through the carboxylation of C(sp<sup>2</sup>)-X bonds with CO<sub>2</sub> including literature published from 2000 to December 2024.</p><h3>Graphical Abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":802,\"journal\":{\"name\":\"Topics in Current Chemistry\",\"volume\":\"383 1\",\"pages\":\"\"},\"PeriodicalIF\":8.6000,\"publicationDate\":\"2025-03-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Topics in Current Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s41061-025-00496-x\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Topics in Current Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s41061-025-00496-x","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Chemistry","Score":null,"Total":0}
CO2 Fixation into Useful Aromatic Carboxylic Acids via C (sp2)–X Bonds Functionalization
Carbon dioxide (CO2) is an abundant and readily available carbon source. Its transformation into high-added-value chemicals is a beneficial strategy, which mitigates greenhouse gas emissions and provides new raw material sources for the chemical industry. Among these chemicals, the aromatic carboxylic acids and derivatives have broad applications in medicine, pesticides, and materials science. Therefore, the carboxylation of C(sp2)-X (X = metal, halide, H, O, or S) bonds with CO2 to efficiently construct aromatic carboxylic acids and their derivatives is a synthetic strategy of significance. This review highlights the recent progress in constructing carboxylic acids and derivatives through the carboxylation of C(sp2)-X bonds with CO2 including literature published from 2000 to December 2024.
期刊介绍：
Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science.
Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community.
In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.
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