煤层气高效抽提关键因素研究:孔隙结构、解吸速率和渗流特征

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yuhuan He, Xijian Li, Junjie Cai, Shoukun Chen, Xianxian Li
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引用次数: 0

摘要

有效开采煤层气是提高煤矿安全生产水平、促进天然气生产和储存的关键战略。为了考察煤层气开采过程中孔隙参数、温压条件下解吸速率、渗流能力等重要变量对煤层气产量的影响。通过低温氮气吸附试验(LTN2A)、不同温度下的甲烷吸附/解吸实验,定量分析了解吸速率常数、初始解吸速率、解吸速率衰减指数随温度和压力的变化规律。利用COMSOL软件模拟了不同储层压力下煤层气的渗流特征。结果表明,样品内部较大的孔隙体积有利于气体吸附。在313.15 K和333.15 K时,QL样品的解吸量比WJB样品高55.65%和48.01%,因为QL样品具有更好的孔隙连通性。随着温度的升高,k、V1、kt三个参数处于较高水平;因此,解吸速率在333.15 K和压力在1 ~ 4 MPa之间达到峰值。此外,WJB样品比QL样品对温度更敏感。COMSOL模拟结果表明,当储层压力低于10 MPa时,储层内甲烷压力释放效果较好。达西渗流速度快且稳定,有利于煤层气的渗流。研究结果揭示了煤层气的解吸和渗流特性与其孔隙结构之间的关系,为煤层气的成功开发提供了经验和理论支持。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Study of Key Factors for Efficient Coalbed Methane Extraction: Pore Structure, Desorption Rate and Seepage Characteristics

Study of Key Factors for Efficient Coalbed Methane Extraction: Pore Structure, Desorption Rate and Seepage Characteristics
Effective coalbed methane extraction is a key strategy for boosting natural gas production and storage in addition to raising the safety of the production standard of coal mines. In order to examine the effects of important variables such as pore parameters, desorption rate under temperature and pressure conditions, and seepage capacity on coalbed methane production during the coalbed methane extraction process. The low-temperature nitrogen adsorption tests (LTN2A), methane adsorption/desorption experiments at various temperatures, and the changes in the desorption rate constants, the initial desorption rate, and the desorption rate decay index with temperature and pressure were quantitatively analyzed. And COMSOL software was used to simulate the seepage characteristics of coalbed methane under various reservoir pressures. The results demonstrated that the large interior pore volumes of the samples are beneficial for gas adsorption. Because of its better pore connectivity, the QL sample had a desorption amount that was 55.65% and 48.01% higher at 313.15 and 333.15 K than the WJB sample. The three parameters of k, V1 and kt are at a high level with increasing temperature; hence, the desorption rate peaks at 333.15 K and pressures between 1 and 4 MPa. Furthermore, the WJB sample is more sensitive to the temperature than the QL sample. The COMSOL simulation shows that the methane pressure inside the reservoir can be released better when the reservoir pressure is below 10 MPa. The Darcy seepage rate is fast and stable, which is favorable for the seepage of coalbed methane. The findings show a relationship between the desorption and seepage properties of CBM and its pore structure, which may offer empirical and theoretical support for the successful development of the CBM.
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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