纳米ZrO2修饰钴- ldh /多孔MgO复合材料光催化去除靛蓝胭脂红

IF 15.8 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING
Tehseen Zehra , Ananda Repycha Safira , Arash Fattah-alhosseini , Mohammad Alkaseem , Mosab Kaseem
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引用次数: 0

摘要

本研究提出了一种新型的光催化体系,利用ZrO₂的独特性质及其与层状双氢氧化物(LDH)膜在等离子体电解氧化(PEO)制备的多孔涂层上的集成。本文首先在硝酸钴和硝酸铁溶液中进行水热处理,然后在70°C的ZrO 2溶液中进行二次水热处理,在poo涂层AZ31镁合金的多孔表面制备了fe - ldh膜。然后将ZrO₂对形态、组成和光催化性能的影响与电泳将ZrO₂纳米颗粒掺入多孔PEO涂层的情况进行了比较。表征结果表明,ZrO 2修饰的LDH涂层呈现出分散的片状结构,比表面积增加,带隙能降低3.14 eV,电子空穴分离增强。实验结果表明,在15分钟内,靛蓝胭脂红的降解率达到99.8%,并且在连续5次循环中具有显著的多循环稳定性,性能没有明显下降。与之前报道的催化剂相比,该系统表现出更快的降解速度和更高的耐久性,强调了其有效和可持续环境修复的潜力。ZrO₂、LDH和PEO的协同整合突出了废水处理的一个有前途的策略,特别是在去除靛蓝胭脂红等持久性有机染料方面。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Decoration of CoFe-LDH/porous MgO composite with ZrO2 nanoparticles for efficient photocatalytic removal of indigo carmine

Decoration of CoFe-LDH/porous MgO composite with ZrO2 nanoparticles for efficient photocatalytic removal of indigo carmine

Decoration of CoFe-LDH/porous MgO composite with ZrO2 nanoparticles for efficient photocatalytic removal of indigo carmine
This study presents a novel photocatalytic system exploiting the unique properties of ZrO₂ and its integration with layered double hydroxide (LDH) films on porous coatings produced via plasma electrolytic oxidation (PEO). Herein, CoFe-LDH films were created on the porous surface of PEO-coated AZ31 Mg alloy using a hydrothermal treatment in cobalt and iron nitrate solutions, followed by a secondary hydrothermal process in a ZrO₂ solution for 10 h at 70 °C. The impact of ZrO₂ on the morphological, compositional, and photocatalytic performance was then compared to the case where ZrO₂ nanoparticles were electrophoretically incorporated into the porous PEO coating. Characterization results revealed that the ZrO₂-modified LDH coatings exhibited a dispersed flake-like structure with an increased surface area, a reduced band gap energy of 3.14 eV, and enhanced electron-hole separation. Experimental results demonstrated an outstanding 99.8% degradation of indigo carmine within 15 mins, with remarkable multi-cycle stability over five consecutive cycles without significant performance decline. This system demonstrates faster degradation rates and greater durability compared to previously reported catalysts, underscoring its potential for effective and sustainable environmental remediation. The synergistic integration of ZrO₂, LDH, and PEO highlights a promising strategy for wastewater treatment, particularly for the removal of persistent organic dyes like indigo carmine.
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来源期刊
Journal of Magnesium and Alloys
Journal of Magnesium and Alloys Engineering-Mechanics of Materials
CiteScore
20.20
自引率
14.80%
发文量
52
审稿时长
59 days
期刊介绍: The Journal of Magnesium and Alloys serves as a global platform for both theoretical and experimental studies in magnesium science and engineering. It welcomes submissions investigating various scientific and engineering factors impacting the metallurgy, processing, microstructure, properties, and applications of magnesium and alloys. The journal covers all aspects of magnesium and alloy research, including raw materials, alloy casting, extrusion and deformation, corrosion and surface treatment, joining and machining, simulation and modeling, microstructure evolution and mechanical properties, new alloy development, magnesium-based composites, bio-materials and energy materials, applications, and recycling.
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